New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family

doi:10.1021/acs.orglett.5b00081

	New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family
	Cao, Pei; Yang, Jing; Miao, Cui-Ping; Yan, Yijun; Ma, Ya-Tuan; Li, Xiao-Nian; Zhao, Li-Xing; Huang, Sheng-Xiong; Zhao,LX (reprint author),Yunnan Univ,Minist Educ,Key Lab Microbial Resources,Kunming 650091,Peoples R China.; zlx70@163.com; sxhuang@mail.kib.ac.cn
	2015-03-06
发表期刊	ORGANIC LETTERS
卷号	17 期号:5 页码:1146-1149
摘要	Duclauxamide A1 (1), a new polyketide-derived heptacyclic oligophenalenone dimer with a N-2-hydroxyethyl moiety, was isolated from Penicillium manginii YIM PH30375. Spectroscopic analysis, X-ray single crystal diffraction, and C-13 NMR DFT calculations confirmed that compound 1 and other duclauxin analogues possess the unified S configuration at C-9', which corrects a long-standing misrepresentation of duclauxins as C-9'R epimers. A plausible biosynthetic pathway for duclauxins is proposed on the basis of previous acetate labeling results for duclauxin and sclerodin.
学科领域	Chemistry, Organic
DOI	10.1021/acs.orglett.5b00081
收录类别	SCI
语种	英语
WOS记录号	WOS:000350841300022
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/20576
专题	植物化学与西部植物资源持续利用国家重点实验室
通讯作者	Zhao,LX (reprint author),Yunnan Univ,Minist Educ,Key Lab Microbial Resources,Kunming 650091,Peoples R China.; zlx70@163.com; sxhuang@mail.kib.ac.cn
推荐引用方式 GB/T 7714	Cao, Pei,Yang, Jing,Miao, Cui-Ping,et al. New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family[J]. ORGANIC LETTERS,2015,17(5):1146-1149.
APA	Cao, Pei.,Yang, Jing.,Miao, Cui-Ping.,Yan, Yijun.,Ma, Ya-Tuan.,...&sxhuang@mail.kib.ac.cn.(2015).New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family.ORGANIC LETTERS,17(5),1146-1149.
MLA	Cao, Pei,et al."New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family".ORGANIC LETTERS 17.5(2015):1146-1149.

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