Salvifarinin A, a neo-clerodane diterpenoid with a 6/5/7 tricyclic skeleton from Salvia farinacea
Fan, Min1,2; Chen, Xue-Jiao1,2; Wu, Xing-De1; Shao, Li-Dong1; Ji, Xu1; Zhao, Qin-Shi1
2018-08-08
发表期刊TETRAHEDRON LETTERS
ISSN0040-4039
卷号59期号:32页码:3065-3068
摘要Salvifarinin A (1), a rearrangement product of Languidulane-type clerodane diterpenoids with a 6/5/7 tricyclic ring skeleton fused with gamma-lactone ring and furan ring, and two new biogenetically related diterpernoids, salvifarinins B (2) and C (3), were isolated from the aerial parts of Salvia farinacea. The absolute configuration of 1 was elucidated by extensive spectroscopic methods, and confirmed by single crystal X-ray diffraction and bio-inspired semisynthesis. The plausible biogenetic pathway was also proposed. Compound 2 displayed a potent effect on reducing hepatic steatosis. (C) 2018 Published by Elsevier Ltd.
关键词Neo-clerodane Diterpenoids Salvia Farinacea Lipid-lowering Activity
语种英语
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文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/61700
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Fan, Min,Chen, Xue-Jiao,Wu, Xing-De,et al. Salvifarinin A, a neo-clerodane diterpenoid with a 6/5/7 tricyclic skeleton from Salvia farinacea[J]. TETRAHEDRON LETTERS,2018,59(32):3065-3068.
APA Fan, Min,Chen, Xue-Jiao,Wu, Xing-De,Shao, Li-Dong,Ji, Xu,&Zhao, Qin-Shi.(2018).Salvifarinin A, a neo-clerodane diterpenoid with a 6/5/7 tricyclic skeleton from Salvia farinacea.TETRAHEDRON LETTERS,59(32),3065-3068.
MLA Fan, Min,et al."Salvifarinin A, a neo-clerodane diterpenoid with a 6/5/7 tricyclic skeleton from Salvia farinacea".TETRAHEDRON LETTERS 59.32(2018):3065-3068.
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