(±)-Evodiakine, A Pair of Rearranged Rutaecarpine-Type Alkaloids From Evodia rutaecarpa.
Li, Yan-Hong; Zhang, Yu; Peng, Li-Yan; Li, Xiao-Nian; Zhao, Qin-Shi; Li, Rong-Tao; Wu, Xing-De
2016
Source PublicationNatural products and bioprospecting
ISSN2192-2195
Volume6Issue:6Pages:291-296
Abstract(±)-Evodiakine (1a and 1b), a pair of rearranged rutaecarpine-type alkaloids with an unprecedented 6/5/5/7/6 ring system, were isolated from the nearly ripe fruits of Evodia rutaecarpa. Separation of the enantiomers have been achieved by chiral HPLC column. The structures of (±)-evodiakine were unambiguously elucidated by 1D and 2D NMR spectra, mass spectrometry, and single-crystal X-ray diffraction. Their absolute configurations were determined by comparison of experimental and calculated electronic circular dichroism spectra. A hypothetical biogenetic pathway for (±)-evodiakine was also proposed. Compounds 1a, 1b, and the racemate (1) were tested for their cytotoxic and anti-inflammatory activities.
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/64861
Collection植物化学与西部植物资源持续利用国家重点实验室
Recommended Citation
GB/T 7714
Li, Yan-Hong,Zhang, Yu,Peng, Li-Yan,et al. (±)-Evodiakine, A Pair of Rearranged Rutaecarpine-Type Alkaloids From Evodia rutaecarpa.[J]. Natural products and bioprospecting,2016,6(6):291-296.
APA Li, Yan-Hong.,Zhang, Yu.,Peng, Li-Yan.,Li, Xiao-Nian.,Zhao, Qin-Shi.,...&Wu, Xing-De.(2016).(±)-Evodiakine, A Pair of Rearranged Rutaecarpine-Type Alkaloids From Evodia rutaecarpa..Natural products and bioprospecting,6(6),291-296.
MLA Li, Yan-Hong,et al."(±)-Evodiakine, A Pair of Rearranged Rutaecarpine-Type Alkaloids From Evodia rutaecarpa.".Natural products and bioprospecting 6.6(2016):291-296.
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