A New Type of Monoterpenoid Indole Alkaloid Precursor from Alstonia rostrata
Cai, Xiang-Hai2; Bao, Mei-Fen2; Zhang, Yu2; Zeng, Chun-Xia1; Liu, Ya-Ping2; Luo, Xiao-Dong2
2011-07-15
发表期刊ORGANIC LETTERS
ISSN1523-7060
卷号13期号:14页码:3568-3571
摘要Currently, all monoterpenoid indole alkaloids (MIAs) have been derived from strictosidine, which originates from the condensation of tryptophan with secologanin in a 1:1 ratio. However, our phytochemical research on Alstonia rostrata revealed a potential new precursor for these compounds. We isolated the alstrostines A and B, and it was determined that they were derived from tryptophan and secologanin In a 1:2 ratio, which supported the presence of a new type of MIA precursor.
关键词Melodinus-tenuicaudatus Strictosidine Scholaris Leaves Constituents Derivatives Henryi
资助信息National Natural Science Foundation of China[30800091]; Ministry of Science and Technology of P. R. China[2009CB522300]; Chinese Academy of Sciences[KSCX2-EW-R-15]
学科领域Chemistry
DOI10.1021/ol200996a
收录类别SCI ; IC
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000292479300005
引用统计
被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/5567
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, SW China Germplasm Bank Wild Species, Kunming 650204, Peoples R China
2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China
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Cai, Xiang-Hai,Bao, Mei-Fen,Zhang, Yu,et al. A New Type of Monoterpenoid Indole Alkaloid Precursor from Alstonia rostrata[J]. ORGANIC LETTERS,2011,13(14):3568-3571.
APA Cai, Xiang-Hai,Bao, Mei-Fen,Zhang, Yu,Zeng, Chun-Xia,Liu, Ya-Ping,&Luo, Xiao-Dong.(2011).A New Type of Monoterpenoid Indole Alkaloid Precursor from Alstonia rostrata.ORGANIC LETTERS,13(14),3568-3571.
MLA Cai, Xiang-Hai,et al."A New Type of Monoterpenoid Indole Alkaloid Precursor from Alstonia rostrata".ORGANIC LETTERS 13.14(2011):3568-3571.
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