Chiral ligands derived from Abrine .2. Oxazolidines as promoters for enantioselective addition of diethylzinc toward aromatic aldehydes
Dai, WM; Zhu, HJ; Hao, XJ
1996-05-01
发表期刊TETRAHEDRON-ASYMMETRY
ISSN0957-4166
卷号7期号:5页码:1245-1248
摘要A number of indole-containing chiral oxazolidines 2a-i have been synthesized from Abrine readily available from the seeds of Abrus precatorius. Catalysis of these oxazolidines for the addition of diethylzinc toward benzaldehyde was examined. A significant role of the substituent(s) in the catalyst on the degree of asymmetric induction was noted. Moderate enantioselectivity up to 59.8% was recorded. Copyright (C) 1996 Published by Elsevier Science Ltd
关键词Reagents
学科领域Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
收录类别sci
语种英语
WOS记录号WOS:A1996UL78900004
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被引频次:38[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/4354
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位CHINESE ACAD SCI,KUNMING INST BOT,KUNMING 650204,PEOPLES R CHINA
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Dai, WM,Zhu, HJ,Hao, XJ. Chiral ligands derived from Abrine .2. Oxazolidines as promoters for enantioselective addition of diethylzinc toward aromatic aldehydes[J]. TETRAHEDRON-ASYMMETRY,1996,7(5):1245-1248.
APA Dai, WM,Zhu, HJ,&Hao, XJ.(1996).Chiral ligands derived from Abrine .2. Oxazolidines as promoters for enantioselective addition of diethylzinc toward aromatic aldehydes.TETRAHEDRON-ASYMMETRY,7(5),1245-1248.
MLA Dai, WM,et al."Chiral ligands derived from Abrine .2. Oxazolidines as promoters for enantioselective addition of diethylzinc toward aromatic aldehydes".TETRAHEDRON-ASYMMETRY 7.5(1996):1245-1248.
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