Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety
Zhu, HJ; Zhao, BT; Dai, WM; Zhou, J; Hao, XJ
1998-08-21
发表期刊TETRAHEDRON-ASYMMETRY
ISSN0957-4166
卷号9期号:16页码:2879-2888
摘要A number of the indole-containing chiral oxazolidines possessing the gem-di-p-tolyl and gem-di-o-tolyl groups at C-5 were synthesized from abrine and the effects of the C-5 and C-2 substituents on the asymmetric induction in catalytic enantioselective addition of diethylzinc to benzaldehyde were examined. A working model is proposed to rationalize the asymmetric catalysis by these chiral oxazolidines. (C) 1998 Elsevier Science Ltd. All rights reserved.
关键词Aromatic-aldehydes Amino-alcohols Aryl Aldehydes Piperazines Promoters Heteroatoms Alkylation Reagents Zinc
学科领域Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
收录类别IC ; SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
WOS记录号WOS:000076005600022
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/4348
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Yunnan, Peoples R China
2.Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Peoples R China
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GB/T 7714
Zhu, HJ,Zhao, BT,Dai, WM,et al. Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety[J]. TETRAHEDRON-ASYMMETRY,1998,9(16):2879-2888.
APA Zhu, HJ,Zhao, BT,Dai, WM,Zhou, J,&Hao, XJ.(1998).Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety.TETRAHEDRON-ASYMMETRY,9(16),2879-2888.
MLA Zhu, HJ,et al."Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety".TETRAHEDRON-ASYMMETRY 9.16(1998):2879-2888.
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