Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety

	Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety
	Zhu, HJ ; Zhao, BT ; Dai, WM ; Zhou, J; Hao, XJ
	1998-08-21
发表期刊	TETRAHEDRON-ASYMMETRY
ISSN	0957-4166
卷号	9 期号:16 页码:2879-2888
摘要	A number of the indole-containing chiral oxazolidines possessing the gem-di-p-tolyl and gem-di-o-tolyl groups at C-5 were synthesized from abrine and the effects of the C-5 and C-2 substituents on the asymmetric induction in catalytic enantioselective addition of diethylzinc to benzaldehyde were examined. A working model is proposed to rationalize the asymmetric catalysis by these chiral oxazolidines. (C) 1998 Elsevier Science Ltd. All rights reserved.
关键词	Aromatic-aldehydes Amino-alcohols Aryl Aldehydes Piperazines Promoters Heteroatoms Alkylation Reagents Zinc
学科领域	Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
收录类别	IC ; SCI
语种	英语
WOS记录号	WOS:000076005600022
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/4348
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Yunnan, Peoples R China 2.Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Peoples R China
推荐引用方式 GB/T 7714	Zhu, HJ,Zhao, BT,Dai, WM,et al. Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety[J]. TETRAHEDRON-ASYMMETRY,1998,9(16):2879-2888.
APA	Zhu, HJ,Zhao, BT,Dai, WM,Zhou, J,&Hao, XJ.(1998).Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety.TETRAHEDRON-ASYMMETRY,9(16),2879-2888.
MLA	Zhu, HJ,et al."Chiral ligands derived from abrine. Part 5. Substituent effects on asymmetric induction in enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral oxazolidines possessing an indole moiety".TETRAHEDRON-ASYMMETRY 9.16(1998):2879-2888.

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