Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes
Dai, WM; Zhu, HJ; Hao, XJ
1996-08-12
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume37Issue:33Pages:5971-5974
AbstractAsymmetric Pictet-Spengler reaction of a number of aldehydes with Abrine methyl ester (1) was performed at room temperature to furnish mainly 3 and high ee was obtained in enantioselective addition of Et(2)Zn with PhCHO catalyzed by chiral 1,2,3,4-tetrahydro-beta-carboline derivatives 5 synthesized from 3. Copyright (C) 1996 Elsevier Science Ltd
KeywordHighly Enantioselective Addition Aprotic Media Enantiospecific Synthesis Amino-alcohols Alkaloids Reagents Stereospecificity Dialkylzincs (-)-suaveoline (-)-raumacline
Subject AreaChemistry, Organic
Indexed Bysci
Language英语
WOS IDWOS:A1996VB81400038
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/4332
Collection植物化学与西部植物资源持续利用国家重点实验室
AffiliationCHINESE ACAD SCI,KUNMING INST BOT,KUNMING 650204,YUNNAN,PEOPLES R CHINA
Recommended Citation
GB/T 7714
Dai, WM,Zhu, HJ,Hao, XJ. Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes[J]. TETRAHEDRON LETTERS,1996,37(33):5971-5974.
APA Dai, WM,Zhu, HJ,&Hao, XJ.(1996).Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes.TETRAHEDRON LETTERS,37(33),5971-5974.
MLA Dai, WM,et al."Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes".TETRAHEDRON LETTERS 37.33(1996):5971-5974.
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