Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes
Dai, WM; Zhu, HJ; Hao, XJ
1996-08-12
发表期刊TETRAHEDRON LETTERS
ISSN0040-4039
卷号37期号:33页码:5971-5974
摘要Asymmetric Pictet-Spengler reaction of a number of aldehydes with Abrine methyl ester (1) was performed at room temperature to furnish mainly 3 and high ee was obtained in enantioselective addition of Et(2)Zn with PhCHO catalyzed by chiral 1,2,3,4-tetrahydro-beta-carboline derivatives 5 synthesized from 3. Copyright (C) 1996 Elsevier Science Ltd
关键词Highly Enantioselective Addition Aprotic Media Enantiospecific Synthesis Amino-alcohols Alkaloids Reagents Stereospecificity Dialkylzincs (-)-suaveoline (-)-raumacline
学科领域Chemistry, Organic
收录类别sci
语种英语
WOS记录号WOS:A1996VB81400038
引用统计
被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/4332
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位CHINESE ACAD SCI,KUNMING INST BOT,KUNMING 650204,YUNNAN,PEOPLES R CHINA
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Dai, WM,Zhu, HJ,Hao, XJ. Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes[J]. TETRAHEDRON LETTERS,1996,37(33):5971-5974.
APA Dai, WM,Zhu, HJ,&Hao, XJ.(1996).Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes.TETRAHEDRON LETTERS,37(33),5971-5974.
MLA Dai, WM,et al."Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes".TETRAHEDRON LETTERS 37.33(1996):5971-5974.
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