LC-UV-Guided Isolation and Structure Determination of Lancolide E: A Nortriterpenoid with a Tetracyclo[5.4.0.0(2,4).0(3,7)]undecane-Bridged System from a "Talented" Schisandra Plant | |
Shi, Yi-Ming; Cai, Song-Liang; Li, Xiao-Nian; Liu, Miao; Shang, Shan-Zhai; Du, Xue; Xiao, Wei-Lie; Pu, Jian-Xin; Sun, Han-Dong | |
2016 | |
发表期刊 | ORGANIC LETTERS |
卷号 | 18期号:1页码:100-103 |
摘要 | Lancolide E (1) featuring a complex tetracyclo[5.4.0.0(2,4).0(3,7)]undecane-bridged system that is constructed by an eight-, a three-, and two five-membered carbon rings in a sterically congested region was obtained in trace amounts from a "talented" schinortriterpenoid producer Schisandra lancifolia. Its structure was fully characterized by combining 2D NMR spectroscopy, theoretical calculations, and X-ray diffraction analysis. The biogenetic pathway of 1 was proposed to involve a Prins cyclization. |
DOI | 10.1021/acs.orglett.5b03334 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000367702400026 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/25437 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
推荐引用方式 GB/T 7714 | Shi, Yi-Ming,Cai, Song-Liang,Li, Xiao-Nian,et al. LC-UV-Guided Isolation and Structure Determination of Lancolide E: A Nortriterpenoid with a Tetracyclo[5.4.0.0(2,4).0(3,7)]undecane-Bridged System from a "Talented" Schisandra Plant[J]. ORGANIC LETTERS,2016,18(1):100-103. |
APA | Shi, Yi-Ming.,Cai, Song-Liang.,Li, Xiao-Nian.,Liu, Miao.,Shang, Shan-Zhai.,...&Sun, Han-Dong.(2016).LC-UV-Guided Isolation and Structure Determination of Lancolide E: A Nortriterpenoid with a Tetracyclo[5.4.0.0(2,4).0(3,7)]undecane-Bridged System from a "Talented" Schisandra Plant.ORGANIC LETTERS,18(1),100-103. |
MLA | Shi, Yi-Ming,et al."LC-UV-Guided Isolation and Structure Determination of Lancolide E: A Nortriterpenoid with a Tetracyclo[5.4.0.0(2,4).0(3,7)]undecane-Bridged System from a "Talented" Schisandra Plant".ORGANIC LETTERS 18.1(2016):100-103. |
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