Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus

	Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus
	Luo, Du-Qiang ; Gao, Yuan ; Yang, Xiao-Long ; Tang, Jian-Guo ; Zhao, Li-Yan ; Liu, Ji-Kai
	2007
发表期刊	HELVETICA CHIMICA ACTA
ISSN	0018-019X
卷号	90 期号:6 页码:1112-1116
摘要	Two new highly oxidized humulane sesquiterpenes, mitissimols F (1) and G (2), were isolated from the fruiting bodies of Lactarius mitissimus. Their structures were elucidated by using extensive spectroscopic techniques including 1D- and 2D-NMR experiments. The absolute configuration of mitissimol F (1) was determined by H-1-NMR resolution of its diastereoisomeric alpha-methoxy-alpha-(trifluoromethyl)benzeneacetates (MTPA). It was shown to be (1S,3E,6S,8R,9R,10S,11R)-8,9:10,11-diepoxy-1,6-dihydroxyhumul-3-en-5-one (=(1S,2R,4R,6S,8E,11S,12R)-6,11-dihydroxy-1,6,10,10-tetramethyl-3,13-dioxatricyclo[10.1.0.0(2.4)]tridec-8-en-7-one).
关键词	Zingiber-aromaticum Zerumbone Metabolites
学科领域	Chemistry ; Multidisciplinary
收录类别	SCI ; IC
语种	英语
WOS记录号	WOS:000247690600006
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/2041
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Hebei Univ, Coll Life Sci, Baoding 071002, Peoples R China 2.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
推荐引用方式 GB/T 7714	Luo, Du-Qiang,Gao, Yuan,Yang, Xiao-Long,et al. Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus[J]. HELVETICA CHIMICA ACTA,2007,90(6):1112-1116.
APA	Luo, Du-Qiang,Gao, Yuan,Yang, Xiao-Long,Tang, Jian-Guo,Zhao, Li-Yan,&Liu, Ji-Kai.(2007).Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus.HELVETICA CHIMICA ACTA,90(6),1112-1116.
MLA	Luo, Du-Qiang,et al."Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus".HELVETICA CHIMICA ACTA 90.6(2007):1112-1116.

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