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题名: Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus
作者: Luo, Du-Qiang; Gao, Yuan; Yang, Xiao-Long; Tang, Jian-Guo; Zhao, Li-Yan; Liu, Ji-Kai
刊名: HELVETICA CHIMICA ACTA
关键词: ZINGIBER-AROMATICUM ; ZERUMBONE ; METABOLITES
英文摘要: Two new highly oxidized humulane sesquiterpenes, mitissimols F (1) and G (2), were isolated from the fruiting bodies of Lactarius mitissimus. Their structures were elucidated by using extensive spectroscopic techniques including 1D- and 2D-NMR experiments. The absolute configuration of mitissimol F (1) was determined by H-1-NMR resolution of its diastereoisomeric alpha-methoxy-alpha-(trifluoromethyl)benzeneacetates (MTPA). It was shown to be (1S,3E,6S,8R,9R,10S,11R)-8,9:10,11-diepoxy-1,6-dihydroxyhumul-3-en-5-one (=(1S,2R,4R,6S,8E,11S,12R)-6,11-dihydroxy-1,6,10,10-tetramethyl-3,13-dioxatricyclo[10.1.0.0(2.4)]tridec-8-en-7-one).
出版日期: 2007
卷号: 90, 期号:6, 页码:1112-1116
语种: 英语
收录类别: SCI ; IC
学科分类: Chemistry; Multidisciplinary
ISSN号: 0018-019X
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.kib.ac.cn/handle/151853/2041
Appears in Collections:植物化学与西部植物资源持续利用国家重点实验室_期刊论文

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作者单位: 1.Hebei Univ, Coll Life Sci, Baoding 071002, Peoples R China
2.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China

Recommended Citation:
Luo, DQ; Gao, Y; Yang, XL; Tang, JG; Zhao, LY; Liu, JK.Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus,HELVETICA CHIMICA ACTA,2007,90(6):1112-1116
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