| Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum | |
| Wang, Fei1,2; Mao, Mei-Fen2; Wei, Guo-Zhu2; Gao, Yuan2; Ren, Fu-Cai2; Liu, Ji-Kai1 | |
| 通讯作者 | Wang,F (reprint author),Chinese Acad Sci,State Key Lab Phytochem & Plant Resources West Ch,Kunming Inst Bot,Kunming 650201,Peoples R China.,wangfei@mail.kib.ac.cn ; jkliu@mail.kib.ac.cn |
| 2013-11-01 | |
| 发表期刊 | PHYTOCHEMISTRY
 |
| ISSN | 0031-9422 |
| 卷号 | 95页码:428-435 |
| 摘要 | Two Daphniphyllum alkaloid and iridoid hybrids with the hitherto unknown decacyclic fused skeletons, hybridaphniphyllines A and B, along with one diamino Daphniphyllum alkaloid, daphnicyclidin I, were isolated from dried stems and leaves of Daphniphyllum longeracemosum. Their structures were elucidated on the basis of extensive spectroscopic analysis, and the absolute configuration of daphnicyclidin I was deduced by the CD exciton chirality method. A biogenetic pathway for 1 and 2 involving natural Diels-Alder cycloaddition is proposed. (C) 2013 Elsevier Ltd. All rights reserved. |
| 关键词 | Daphniphyllum Longeracemosum Daphniphyllaceae C-22 Nor-daphniphyllum Alkaloid Alkaloid And Iridoid Hybrid Hybridaphniphylline Diels-alder Cycloaddition |
| 学科领域 | Biochemistry & Molecular Biology ; Plant Sciences |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000326901500040 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.kib.ac.cn/handle/151853/17409 |
| 专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China 2.BioBioPha Co Ltd, Kunming 650201, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Fei,Mao, Mei-Fen,Wei, Guo-Zhu,et al. Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum[J]. PHYTOCHEMISTRY,2013,95:428-435. |
| APA | Wang, Fei,Mao, Mei-Fen,Wei, Guo-Zhu,Gao, Yuan,Ren, Fu-Cai,&Liu, Ji-Kai.(2013).Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum.PHYTOCHEMISTRY,95,428-435. |
| MLA | Wang, Fei,et al."Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum".PHYTOCHEMISTRY 95(2013):428-435. |
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