Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum
Wang, Fei1,2; Mao, Mei-Fen2; Wei, Guo-Zhu2; Gao, Yuan2; Ren, Fu-Cai2; Liu, Ji-Kai1
2013-11-01
发表期刊PHYTOCHEMISTRY
ISSN0031-9422
卷号95页码:428-435
摘要Two Daphniphyllum alkaloid and iridoid hybrids with the hitherto unknown decacyclic fused skeletons, hybridaphniphyllines A and B, along with one diamino Daphniphyllum alkaloid, daphnicyclidin I, were isolated from dried stems and leaves of Daphniphyllum longeracemosum. Their structures were elucidated on the basis of extensive spectroscopic analysis, and the absolute configuration of daphnicyclidin I was deduced by the CD exciton chirality method. A biogenetic pathway for 1 and 2 involving natural Diels-Alder cycloaddition is proposed. (C) 2013 Elsevier Ltd. All rights reserved.
关键词Daphniphyllum Longeracemosum Daphniphyllaceae C-22 Nor-daphniphyllum Alkaloid Alkaloid And Iridoid Hybrid Hybridaphniphylline Diels-alder Cycloaddition
资助信息Large-scale Compound Library project of National Development and Reform Commission of China;National Basic Research Program of China (973 Program) [2009CB522300];"Western Light" talents training program of Chinese Academy of Sciences
学科领域Biochemistry & Molecular Biology ; Plant Sciences
收录类别SCI ; IC
语种英语
WOS研究方向Biochemistry & Molecular Biology ; Plant Sciences
WOS类目Biochemistry & Molecular Biology ; Plant Sciences
WOS记录号WOS:000326901500040
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被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/17409
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China
2.BioBioPha Co Ltd, Kunming 650201, Peoples R China
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Wang, Fei,Mao, Mei-Fen,Wei, Guo-Zhu,et al. Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum[J]. PHYTOCHEMISTRY,2013,95:428-435.
APA Wang, Fei,Mao, Mei-Fen,Wei, Guo-Zhu,Gao, Yuan,Ren, Fu-Cai,&Liu, Ji-Kai.(2013).Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum.PHYTOCHEMISTRY,95,428-435.
MLA Wang, Fei,et al."Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum".PHYTOCHEMISTRY 95(2013):428-435.
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