Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua | |
Dong, Liao-Bin1,2; Gao, Xiu1,2; Liu, Fei1,2; He, Juan1; Wu, Xing-De1; Li, Yan1; Zhao, Qin-Shi1 | |
通讯作者 | Zhao, QS (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China. ; qinshizhao@mail.kib.ac.cn |
2013-07-19 | |
发表期刊 | ORGANIC LETTERS |
ISSN | 1523-7060 |
卷号 | 15期号:14页码:3570-3573 |
摘要 | A new pentacyclic (5/6/6/6/7) Lycopodium alkaloid named isopalhinine A (1), which possesses a sterically congested architecture built with a tricyclo[4.3.1.0(3,7)]decane (isotwistane) moiety and a 1-azabicyclo[4.3.1]decane moiety, and palhinines B (2) and C (3) were isolated from Palhinhaea cernua. The structure and absolute configuration of 1 were elucidated by a combination of NMR spectra, optical rotation calculation, and X-ray diffraction experiment. A possible biogenetic pathway was also proposed. |
关键词 | Unprecedented Skeleton A-c Japonicum Palhinine |
学科领域 | Chemistry, Organic |
收录类别 | SCI ; IC |
语种 | 英语 |
WOS记录号 | WOS:000322210600022 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/16735 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Dong, Liao-Bin,Gao, Xiu,Liu, Fei,et al. Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua[J]. ORGANIC LETTERS,2013,15(14):3570-3573. |
APA | Dong, Liao-Bin.,Gao, Xiu.,Liu, Fei.,He, Juan.,Wu, Xing-De.,...&Zhao, Qin-Shi.(2013).Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua.ORGANIC LETTERS,15(14),3570-3573. |
MLA | Dong, Liao-Bin,et al."Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua".ORGANIC LETTERS 15.14(2013):3570-3573. |
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