Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua
Dong, Liao-Bin1,2; Gao, Xiu1,2; Liu, Fei1,2; He, Juan1; Wu, Xing-De1; Li, Yan1; Zhao, Qin-Shi1
2013-07-19
发表期刊ORGANIC LETTERS
ISSN1523-7060
卷号15期号:14页码:3570-3573
摘要A new pentacyclic (5/6/6/6/7) Lycopodium alkaloid named isopalhinine A (1), which possesses a sterically congested architecture built with a tricyclo[4.3.1.0(3,7)]decane (isotwistane) moiety and a 1-azabicyclo[4.3.1]decane moiety, and palhinines B (2) and C (3) were isolated from Palhinhaea cernua. The structure and absolute configuration of 1 were elucidated by a combination of NMR spectra, optical rotation calculation, and X-ray diffraction experiment. A possible biogenetic pathway was also proposed.
关键词Unprecedented Skeleton A-c Japonicum Palhinine
资助信息National Natural Science Foundation [U0932602, 90813004]; National Basic Research Program (973 Program) of China [2011CB915503, 2009CB522303]
学科领域Chemistry, Organic
收录类别SCI ; IC
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000322210600022
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被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/16735
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Dong, Liao-Bin,Gao, Xiu,Liu, Fei,et al. Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua[J]. ORGANIC LETTERS,2013,15(14):3570-3573.
APA Dong, Liao-Bin.,Gao, Xiu.,Liu, Fei.,He, Juan.,Wu, Xing-De.,...&Zhao, Qin-Shi.(2013).Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua.ORGANIC LETTERS,15(14),3570-3573.
MLA Dong, Liao-Bin,et al."Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua".ORGANIC LETTERS 15.14(2013):3570-3573.
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