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题名: Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua
作者: Dong, Liao-Bin1, 2; Gao, Xiu1, 2; Liu, Fei1, 2; He, Juan1; Wu, Xing-De1; null(李艳)1; null(赵勤实)1
刊名: ORGANIC LETTERS
关键词: UNPRECEDENTED SKELETON ; A-C ; JAPONICUM ; PALHININE
英文摘要: A new pentacyclic (5/6/6/6/7) Lycopodium alkaloid named isopalhinine A (1), which possesses a sterically congested architecture built with a tricyclo[4.3.1.0(3,7)]decane (isotwistane) moiety and a 1-azabicyclo[4.3.1]decane moiety, and palhinines B (2) and C (3) were isolated from Palhinhaea cernua. The structure and absolute configuration of 1 were elucidated by a combination of NMR spectra, optical rotation calculation, and X-ray diffraction experiment. A possible biogenetic pathway was also proposed.
出版日期: 2013-07-19
卷号: 15, 期号:14, 页码:3570-3573
语种: 英语
收录类别: SCI ; IC
学科分类: Chemistry, Organic
ISSN号: 1523-7060
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.kib.ac.cn/handle/151853/16735
Appears in Collections:植物化学与西部植物资源持续利用国家重点实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Dong, Liao-Bin; Gao, Xiu; Liu, Fei; He, Juan; Wu, Xing-De; Li, Yan; Zhao, Qin-Shi.Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua,ORGANIC LETTERS,2013,15(14):3570-3573
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