Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N
Zhou, Min1,2; Geng, Hui-Chun1,2; Zhang, Hai-Bo1; Dong, Ke1; Wang, Wei-Guang1,2; Du, Xue1; Li, Xiao-Nian1; He, Fei1; Qin, Hong-Bo1; Li, Yan1; Pu, Jian-Xin1; Sun, Han-Dong1
Corresponding AuthorPu, JX (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China.,pujianxin@mail.kib.ac.cn ; hdsun@mail.kib.ac.cn
2013-01-18
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume15Issue:2Pages:314-317
AbstractScopariusins A-C (1-3), three novel rearranged ent-halimanoids with a bicycle[5.4.0]undecane ring system, two new normal ent-halimanoids (4 and 5), and a new ent-clerodanoid (6) were isolated from Isodon scoparius. Moreover, a biomimetic transformation from the ent-clerodanoid to the normal and the rearranged ent-halimane diterpenoids was successfully accomplished, which not only validated the biogenetic hypothesis in this plant but also confirmed the absolute configurations of 1 and 5.
KeywordSkeleton
Subject AreaChemistry
Indexed BySCI ; IC ; CCR
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000314007700021
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/16204
Collection植物化学与西部植物资源持续利用国家重点实验室
Affiliation1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Min,Geng, Hui-Chun,Zhang, Hai-Bo,et al. Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N[J]. ORGANIC LETTERS,2013,15(2):314-317.
APA Zhou, Min.,Geng, Hui-Chun.,Zhang, Hai-Bo.,Dong, Ke.,Wang, Wei-Guang.,...&Sun, Han-Dong.(2013).Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N.ORGANIC LETTERS,15(2),314-317.
MLA Zhou, Min,et al."Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N".ORGANIC LETTERS 15.2(2013):314-317.
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