Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N

	Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N
	Zhou, Min 1,2; Geng, Hui-Chun 1,2; Zhang, Hai-Bo 1; Dong, Ke 1; Wang, Wei-Guang 1,2; Du, Xue 1; Li, Xiao-Nian 1; He, Fei 1; Qin, Hong-Bo1 ; Li, Yan1 ; Pu, Jian-Xin1 ; Sun, Han-Dong1
通讯作者	Pu, JX (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China.，pujianxin@mail.kib.ac.cn ; hdsun@mail.kib.ac.cn
	2013-01-18
发表期刊	ORGANIC LETTERS
ISSN	1523-7060
卷号	15 期号:2 页码:314-317
摘要	Scopariusins A-C (1-3), three novel rearranged ent-halimanoids with a bicycle[5.4.0]undecane ring system, two new normal ent-halimanoids (4 and 5), and a new ent-clerodanoid (6) were isolated from Isodon scoparius. Moreover, a biomimetic transformation from the ent-clerodanoid to the normal and the rearranged ent-halimane diterpenoids was successfully accomplished, which not only validated the biogenetic hypothesis in this plant but also confirmed the absolute configurations of 1 and 5.
关键词	Skeleton
学科领域	Chemistry
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000314007700021
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/16204
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Min,Geng, Hui-Chun,Zhang, Hai-Bo,et al. Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N[J]. ORGANIC LETTERS,2013,15(2):314-317.
APA	Zhou, Min.,Geng, Hui-Chun.,Zhang, Hai-Bo.,Dong, Ke.,Wang, Wei-Guang.,...&Sun, Han-Dong.(2013).Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N.ORGANIC LETTERS,15(2),314-317.
MLA	Zhou, Min,et al."Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N".ORGANIC LETTERS 15.2(2013):314-317.

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