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题名: Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N
作者: Zhou, Min1, 2; Geng, Hui-Chun1, 2; Zhang, Hai-Bo1; Dong, Ke1; Wang, Wei-Guang1, 2; Du, Xue1; Li, Xiao-Nian1; He, Fei1; null(秦红波)1; null(李艳)1; Pu, Jian-Xin1; null(孙汉董)1
刊名: ORGANIC LETTERS
关键词: SKELETON
英文摘要: Scopariusins A-C (1-3), three novel rearranged ent-halimanoids with a bicycle[5.4.0]undecane ring system, two new normal ent-halimanoids (4 and 5), and a new ent-clerodanoid (6) were isolated from Isodon scoparius. Moreover, a biomimetic transformation from the ent-clerodanoid to the normal and the rearranged ent-halimane diterpenoids was successfully accomplished, which not only validated the biogenetic hypothesis in this plant but also confirmed the absolute configurations of 1 and 5.
出版日期: 2013-01-18
卷号: 15, 期号:2, 页码:314-317
语种: 英语
收录类别: SCI ; IC ; CCR
学科分类: Chemistry
ISSN号: 1523-7060
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.kib.ac.cn/handle/151853/16204
Appears in Collections:植物化学与西部植物资源持续利用国家重点实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650201, Yunnan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China

Recommended Citation:
Zhou, Min; Geng, Hui-Chun; Zhang, Hai-Bo; Dong, Ke; Wang, Wei-Guang; Du, Xue; Li, Xiao-Nian; He, Fei; Qin, Hong-Bo; Li, Yan; Pu, Jian-Xin; Sun, Han-Dong.Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N,ORGANIC LETTERS,2013,15(2):314-317
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