Phytocannabinoid-like meroterpenoids from twigs and leaves of Rhododendron spinuliferum

doi:10.1016/j.phytochem.2024.114241

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	Phytocannabinoid-like meroterpenoids from twigs and leaves of Rhododendron spinuliferum
	Luo, E-E; Yang, Wu-Fen; Wang, Zhao-Jie; Chen, Ling-Yun; Yu, Mu-Yuan; Luo, Xiao-Dong; Qin, Xu-Jie
	2024
发表期刊	PHYTOCHEMISTRY
ISSN	0031-9422
卷号	228 页码:114241
摘要	Six pairs of previously undescribed enantiomeric phytocannabinoid-like meroterpenoids, (+/-)-spinulinoids A-F, and two naturally occurring compounds, (+)-rhododaurichromanic acid A and (E)-4-((3,7-dimethylocta-2,6- dien-1-yl)oxy)benzoic acid, together with one known congener, (-)-rhododaurichromanic acid A, were obtained from the twigs and leaves of Rhododendron spinuliferum. Their structures were established by their extensive spectral data (NMR and HRESIMS), ECD calculations, and single-crystal X-ray diffraction data. Spinulinoids A and B are unprecedented phytocannabinoid-like meroterpenoids constructed by the resorcinol moiety and a /3-bisabolene unit, whereas spinulinoid C represents a rare adduct of quinone and /3-bisabolene with a tricyclic 6/ 6/6 ring system.
DOI	10.1016/j.phytochem.2024.114241
WOS记录号	WOS:001296291000001
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/76059
专题	中国科学院昆明植物研究所
推荐引用方式 GB/T 7714	Luo, E-E,Yang, Wu-Fen,Wang, Zhao-Jie,et al. Phytocannabinoid-like meroterpenoids from twigs and leaves of Rhododendron spinuliferum[J]. PHYTOCHEMISTRY,2024,228:114241.
APA	Luo, E-E.,Yang, Wu-Fen.,Wang, Zhao-Jie.,Chen, Ling-Yun.,Yu, Mu-Yuan.,...&Qin, Xu-Jie.(2024).Phytocannabinoid-like meroterpenoids from twigs and leaves of Rhododendron spinuliferum.PHYTOCHEMISTRY,228,114241.
MLA	Luo, E-E,et al."Phytocannabinoid-like meroterpenoids from twigs and leaves of Rhododendron spinuliferum".PHYTOCHEMISTRY 228(2024):114241.

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