Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone
Long, Yang1,2,3; Ding, Yiming2,3,4; Wu, Hai2,3,4; Qu, Chunlei2,3,4; Liang, Hong2,3,4; Zhang, Min2,3,4; Zhao, Xiaoli2,3,4; Long, Xianwen2,3,4; Wang, Shu1; Puno, Pema-Tenzin2,3; Deng, Jun2,3
Corresponding AuthorDeng, Jun(dengjun@mail.kib.ac.cn)
2019-11-08
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Pages6
AbstractThe first copper-catalyzed intermolecular [5+2] homodimerization of hydroxy p-quinone is presented, furnishing bicyclo[3.2.1]octadienone core structures in typically good yields and excellent diastereoselectivities. Applying this synthetic approach enables a concise nine-step total synthesis of (-)-perezoperezone from commercially available 3,5-dimethoxytoluene.
Keyword5+2 cycloaddition dimerization natural products perezoperezone total synthesis
DOI10.1002/anie.201911978
Indexed BySCI ; SCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000495083600001
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/70980
Collection植物化学与西部植物资源持续利用国家重点实验室
Corresponding AuthorDeng, Jun
Affiliation1.Sichuan Univ, West China Sch Pharm, Dept Med Nat Prod, Chengdu 610041, Sichuan, Peoples R China
2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, 132 Lanhei Rd, Kunming, Yunnan, Peoples R China
3.Chinese Acad Sci, Kunming Inst Bot, Yunnan Key Lab Nat Med Chem, 132 Lanhei Rd, Kunming, Yunnan, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Long, Yang,Ding, Yiming,Wu, Hai,et al. Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019:6.
APA Long, Yang.,Ding, Yiming.,Wu, Hai.,Qu, Chunlei.,Liang, Hong.,...&Deng, Jun.(2019).Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,6.
MLA Long, Yang,et al."Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019):6.
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