Detoxification of Plant Aromatic Abietanoids via Cleavage of the Benzene Ring into 11,12-Seco-diterpene Polyenes by a Specialist Insect of Leucosceptrum canum

doi:10.1021/acs.orglett.9b04044

	Detoxification of Plant Aromatic Abietanoids via Cleavage of the Benzene Ring into 11,12-Seco-diterpene Polyenes by a Specialist Insect of Leucosceptrum canum
	Guo, Kai 1,2,3,4; Liu, Yan 1,2; Luo, Shi-Hong1,2 ; Liu, Yan-Chun1,2 ; Li, De-Sen 1,2,4; Li, Wen-Yuan 1,2,4; Li, Sheng-Hong1,2
Corresponding Author	Li, Sheng-Hong(shli@mail.kib.ac.cn)
	2020-01-03
Source Publication	ORGANIC LETTERS
ISSN	1523-7060
Volume	22 Issue:1 Pages:126-129
Abstract	Leaves of Leucosceptrum canum harbor abundant toxic aromatic abietanoids, and they are rarely attacked by insect herbivores, except for the larvae of Nacna malachitis. The excrements of the insect that fed on L. canum leaves were investigated, leading to the isolation and identification of two unprecedented 11,12-seco-abietane diterpene polyenes: nacnabietanins A (1) and B (2). This discovery heralds a unique detoxification mechanism of plant aromatic abietanoids by insects through enzymatic cleavage of stable benzene rings into more easily degraded polyenes.
DOI	10.1021/acs.orglett.9b04044
Indexed By	SCI ; SCI
Language	英语
WOS ID	WOS:000506088700026
Citation statistics	Cited Times:4[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.kib.ac.cn/handle/151853/70518
Collection	植物化学与西部植物资源持续利用国家重点实验室
Corresponding Author	Li, Sheng-Hong
Affiliation	1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Yunnan, Peoples R China 2.Chinese Acad Sci, Yunnan Key Lab Nat Med Chem, Kunming Inst Bot, Kunming 650201, Yunnan, Peoples R China 3.Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation GB/T 7714	Guo, Kai,Liu, Yan,Luo, Shi-Hong,et al. Detoxification of Plant Aromatic Abietanoids via Cleavage of the Benzene Ring into 11,12-Seco-diterpene Polyenes by a Specialist Insect of Leucosceptrum canum[J]. ORGANIC LETTERS,2020,22(1):126-129.
APA	Guo, Kai.,Liu, Yan.,Luo, Shi-Hong.,Liu, Yan-Chun.,Li, De-Sen.,...&Li, Sheng-Hong.(2020).Detoxification of Plant Aromatic Abietanoids via Cleavage of the Benzene Ring into 11,12-Seco-diterpene Polyenes by a Specialist Insect of Leucosceptrum canum.ORGANIC LETTERS,22(1),126-129.
MLA	Guo, Kai,et al."Detoxification of Plant Aromatic Abietanoids via Cleavage of the Benzene Ring into 11,12-Seco-diterpene Polyenes by a Specialist Insect of Leucosceptrum canum".ORGANIC LETTERS 22.1(2020):126-129.

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