Copper-catalyzed amination of an -C(sp(3))-H bond in inactivated ethers to synthesize alpha-aminonitriles
Yuan, Zaifeng1,2; Zhu, Chunyu1; Ma, Zhixian1; Xia, Chengfeng1
2018-10-07
发表期刊CHEMICAL COMMUNICATIONS
ISSN1359-7345
卷号54期号:78页码:11033-11036
摘要A copper-catalyzed functionalization of inert cyclic ethers was developed to provide -aminonitriles via a cascade oxidation/amination/ring-opening/cyanation reaction. A series of highly versatile -aminonitriles were obtained from primary or secondary anilines, and heterocyclic and aliphatic amines with high yields. This process features excellent functional group tolerance, a broad substrate scope, and high activity under ambient conditions.
资助信息National Natural Science Foundation of China; Program for Changjiang Scholars and Innovative Research Team in University
DOI10.1039/c8cc06111d
语种英语
资助项目National Natural Science Foundation of China[21572236] ; Program for Changjiang Scholars and Innovative Research Team in University[IRT_17R94]
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000445767500020
出版者ROYAL SOC CHEMISTRY
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/62547
专题植物化学与西部植物资源持续利用国家重点实验室
通讯作者Xia, Chengfeng
作者单位1.Yunnan Univ, Sch Chem Sci & Technol, Lib Yunnan Univ, Key Lab Med Chem Nat Resources,Minist Educ & Yunn, 2 North Cuihu Rd, Kunming 650091, Yunnan, Peoples R China
2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, 132 Lanhei Rd, Kunming 650201, Yunnan, Peoples R China
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Yuan, Zaifeng,Zhu, Chunyu,Ma, Zhixian,et al. Copper-catalyzed amination of an -C(sp(3))-H bond in inactivated ethers to synthesize alpha-aminonitriles[J]. CHEMICAL COMMUNICATIONS,2018,54(78):11033-11036.
APA Yuan, Zaifeng,Zhu, Chunyu,Ma, Zhixian,&Xia, Chengfeng.(2018).Copper-catalyzed amination of an -C(sp(3))-H bond in inactivated ethers to synthesize alpha-aminonitriles.CHEMICAL COMMUNICATIONS,54(78),11033-11036.
MLA Yuan, Zaifeng,et al."Copper-catalyzed amination of an -C(sp(3))-H bond in inactivated ethers to synthesize alpha-aminonitriles".CHEMICAL COMMUNICATIONS 54.78(2018):11033-11036.
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