One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone

doi:10.1016/j.tetlet.2011.03.081

	One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone
	Wang, Gang-Qiang 1,2; Wei, Kun 1; Zhang, Lin 1; Feng, Tao 1; Wang, Fei 1; Wang, Qiu-An 2; Liu, Ji-Kai 1
通讯作者	Liu, JK (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
	2011-05-25
发表期刊	TETRAHEDRON LETTERS
ISSN	0040-4039
卷号	52 期号:21 页码:2719-2721
摘要	A one-step biomimetic synthesis of racemic linderspirone and bi-liderone from methyllinderone has been achieved, which probably reflects the biosynthesis of the natural products. There are few naturally occurring substances that appear to be formed by a [4+4] or [4+2] cycloaddition. We proposed that the [4+4] dimerization of methyllinderone proceeds via a stepwise mechanism involving a diradical intermediate. (C) 2011 Elsevier Ltd. All rights reserved.
关键词	Biomimetic Synthesis Linderspirone Bi-liderone Methyllinderone
学科领域	Chemistry
DOI	10.1016/j.tetlet.2011.03.081
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000290602100026
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/5561
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China 2.Hunan Univ, Sch Chem & Chem Engn, Changsha 410082, Peoples R China
推荐引用方式 GB/T 7714	Wang, Gang-Qiang,Wei, Kun,Zhang, Lin,et al. One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone[J]. TETRAHEDRON LETTERS,2011,52(21):2719-2721.
APA	Wang, Gang-Qiang.,Wei, Kun.,Zhang, Lin.,Feng, Tao.,Wang, Fei.,...&Liu, Ji-Kai.(2011).One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone.TETRAHEDRON LETTERS,52(21),2719-2721.
MLA	Wang, Gang-Qiang,et al."One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone".TETRAHEDRON LETTERS 52.21(2011):2719-2721.

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