One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone
Wang, Gang-Qiang1,2; Wei, Kun1; Zhang, Lin1; Feng, Tao1; Wang, Fei1; Wang, Qiu-An2; Liu, Ji-Kai1
Corresponding AuthorLiu, JK (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
2011-05-25
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume52Issue:21Pages:2719-2721
AbstractA one-step biomimetic synthesis of racemic linderspirone and bi-liderone from methyllinderone has been achieved, which probably reflects the biosynthesis of the natural products. There are few naturally occurring substances that appear to be formed by a [4+4] or [4+2] cycloaddition. We proposed that the [4+4] dimerization of methyllinderone proceeds via a stepwise mechanism involving a diradical intermediate. (C) 2011 Elsevier Ltd. All rights reserved.
KeywordBiomimetic Synthesis Linderspirone Bi-liderone Methyllinderone
Subject AreaChemistry
DOI10.1016/j.tetlet.2011.03.081
Indexed BySCI ; CCR
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000290602100026
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/5561
Collection植物化学与西部植物资源持续利用国家重点实验室
Affiliation1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
2.Hunan Univ, Sch Chem & Chem Engn, Changsha 410082, Peoples R China
Recommended Citation
GB/T 7714
Wang, Gang-Qiang,Wei, Kun,Zhang, Lin,et al. One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone[J]. TETRAHEDRON LETTERS,2011,52(21):2719-2721.
APA Wang, Gang-Qiang.,Wei, Kun.,Zhang, Lin.,Feng, Tao.,Wang, Fei.,...&Liu, Ji-Kai.(2011).One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone.TETRAHEDRON LETTERS,52(21),2719-2721.
MLA Wang, Gang-Qiang,et al."One-step biomimetic synthesis of (+/-)-linderaspirone A and (+/-)-bi-linderone".TETRAHEDRON LETTERS 52.21(2011):2719-2721.
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