Selected Mutations Revealed Intermediates and Key Precursors in the Biosynthesis of Polyketide-Terpenoid Hybrid Sesquiterpenyl Epoxy-cyclohexenoids
Teng, Lin-Lin1,2,3; Song, Tian-Yang1,2; Xu, Zi-Fei1,2; Liu, Xiao1,2; Dai, Rong1,2; Chen, Yong-Hong1,2; Li, Sheng-Hong3; Zhang, Ke-Qin1,2; Niu, Xue-Mei1,2
2017-07-21
发表期刊ORGANIC LETTERS
ISSN1523-7060
卷号19期号:14页码:3923-3926
摘要Sesquiterpenyl epoxy-cydohexenoids (SECs) show impressive biological activities. However, the key pathways for SECs still remain, unambiguous. Unexpectedly, 11 new SECs and derivatives with diverse oxidation patterns were isolated after the deletion of gene 274. A high accumulation of toluquiriol and its new glycosides in mutant Delta 276 and further isolation of the most crucial. precursors farnesy1 hydroquinone, farnesyl quinone, and three new derivatives froth mutant Delta 278-confirm that farnesylation at toluquinol is the key step for SECs.
关键词Fungus Arthrobotrys-oligospora Morphological Regulatory Arthrosporols Metabolite Production Antibiotics Disruption Mechanisms Patulin
收录类别SCI
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/54942
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Yunnan Univ, Sch Life Sci, State Key Lab Conservat & Utilizat Bioresources, Kunming 650091, Yunnan, Peoples R China
2.Yunnan Univ, Sch Life Sci, Key Lab Microbial Resources, Minist Educ, Kunming 650091, Yunnan, Peoples R China
3.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Yunnan, Peoples R China
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Teng, Lin-Lin,Song, Tian-Yang,Xu, Zi-Fei,et al. Selected Mutations Revealed Intermediates and Key Precursors in the Biosynthesis of Polyketide-Terpenoid Hybrid Sesquiterpenyl Epoxy-cyclohexenoids[J]. ORGANIC LETTERS,2017,19(14):3923-3926.
APA Teng, Lin-Lin.,Song, Tian-Yang.,Xu, Zi-Fei.,Liu, Xiao.,Dai, Rong.,...&Niu, Xue-Mei.(2017).Selected Mutations Revealed Intermediates and Key Precursors in the Biosynthesis of Polyketide-Terpenoid Hybrid Sesquiterpenyl Epoxy-cyclohexenoids.ORGANIC LETTERS,19(14),3923-3926.
MLA Teng, Lin-Lin,et al."Selected Mutations Revealed Intermediates and Key Precursors in the Biosynthesis of Polyketide-Terpenoid Hybrid Sesquiterpenyl Epoxy-cyclohexenoids".ORGANIC LETTERS 19.14(2017):3923-3926.
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