Aspergilasines A-D: Four Merocytochalasans with New Carbon Skeletons from Aspergillus flavipes QCS12 | |
Wei, Guangzheng1; Chen, Chunmei1; Tong, Qingyi1; Huang, Jinfeng1; Wang, Wenjing1; Wu, Zhaodi1; Yang, Jing2![]() | |
2017-08-18 | |
发表期刊 | ORGANIC LETTERS
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ISSN | 1523-7060 |
卷号 | 19期号:16页码:4399-4402 |
摘要 | Aspergilasines A-D (1-4), four rnerocytochalasans with new skeletons, were isolated from the liquid culture broth of Aspergillits flavipe QCS12. Aspergilasine A (1) possesses a uniquely caged pentacyclo [7.2,0.1(4,11).0(2,7).0(5,,10)] dodecane skeleton With an unexpected cyclobutane ring that fotmed by the fusion of two epicoccine moieties via two [3 + 2] cycloadditions. Aspergilasies B-D (2-4) are key bioSyhthetic intermediates of epicochalasine B that fit well with our previous biosynthetic proposal. |
关键词 | Fungus Periconia Sp Ring-system Chaetomium-globosum Cytochalasans Alkaloids Origin Dimer |
学科领域 | Chemistry, Organic |
DOI | 10.1021/acs.orglett.7b02146 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000408285600062 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/54917 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Huazhong Univ Sci & Technol, Tongji Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Hubei, Peoples R China 2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Wei, Guangzheng,Chen, Chunmei,Tong, Qingyi,et al. Aspergilasines A-D: Four Merocytochalasans with New Carbon Skeletons from Aspergillus flavipes QCS12[J]. ORGANIC LETTERS,2017,19(16):4399-4402. |
APA | Wei, Guangzheng.,Chen, Chunmei.,Tong, Qingyi.,Huang, Jinfeng.,Wang, Wenjing.,...&Zhang, Yonghui.(2017).Aspergilasines A-D: Four Merocytochalasans with New Carbon Skeletons from Aspergillus flavipes QCS12.ORGANIC LETTERS,19(16),4399-4402. |
MLA | Wei, Guangzheng,et al."Aspergilasines A-D: Four Merocytochalasans with New Carbon Skeletons from Aspergillus flavipes QCS12".ORGANIC LETTERS 19.16(2017):4399-4402. |
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