Crystal and Molecular Structure of (S)-N-(2-Hydroxyphenyl)pyrrolidine-2-carboxamide | |
Chen, Gang1; Tang, Ying1; Zhang, Qun-Zheng1; Meng, Mei1; Hao, Xiao-Jiang2 | |
通讯作者 | Chen, G (reprint author), Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China |
2011-02-01 | |
发表期刊 | JOURNAL OF CHEMICAL CRYSTALLOGRAPHY |
ISSN | 1074-1542 |
卷号 | 41期号:2页码:251-254 |
摘要 | (S)-N-(2-Hydroxyphenyl)pyrrolidine-2-carboxamide was synthesized from Cbz-l-proline through two steps and characterized by NMR and MS. The crystal structure was determined from single-crystal X-ray diffraction data. It crystallizes in the monoclinic space group, P2(1), with unit cell dimensions a = 7.284(6) angstrom, b = 10.262(9) angstrom, and c = 7.975(7) angstrom, alpha = 90.00 degrees, beta = 114.451(14)degrees, gamma = 90.00 degrees and Z = 2. The absolute configuration of the chiral center is determined as S. In the crystal structure, intermolecular and intramolecular hydrogen bonds are responsible for the formation of a 1-dimensional network. |
关键词 | L-proline (s)-n-(2-hydroxyphenyl) Pyrrolidine-2-carboxamide X-ray Structure |
学科领域 | Crystallography ; Spectroscopy |
DOI | 10.1007/s10870-010-9935-z |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000286469800030 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/5355 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China 2.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Gang,Tang, Ying,Zhang, Qun-Zheng,et al. Crystal and Molecular Structure of (S)-N-(2-Hydroxyphenyl)pyrrolidine-2-carboxamide[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,2011,41(2):251-254. |
APA | Chen, Gang,Tang, Ying,Zhang, Qun-Zheng,Meng, Mei,&Hao, Xiao-Jiang.(2011).Crystal and Molecular Structure of (S)-N-(2-Hydroxyphenyl)pyrrolidine-2-carboxamide.JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,41(2),251-254. |
MLA | Chen, Gang,et al."Crystal and Molecular Structure of (S)-N-(2-Hydroxyphenyl)pyrrolidine-2-carboxamide".JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 41.2(2011):251-254. |
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