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题名: 1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones
作者: Fuji, K ; Yang, XS ; Tanaka, K ; Asakawa, N ; null(郝小江)
刊名: TETRAHEDRON LETTERS
关键词: ONE-STEP SYNTHESIS ; ESTERS
英文摘要: Half esters (R)-5 of 1,1'-binaphthalene-8,8'-diol undergo 1,4-addition of lithium dialkyl cuprates followed by formal 1,2-addition to give beta-substituted ketones (S)-6 or (S)-7 with high enantioselectivity (96 similar to 100% ee). A brief discussion of the mechanism is presented. Copyright (C) 1996 Elsevier Science Ltd
出版日期: 1996
卷号: 37, 期号:41, 页码:7373-7376
语种: 英语
ISSN号: 0040-4039
内容类型: 期刊论文
URI标识: http://ir.kib.ac.cn/handle/151853/4344
Appears in Collections:植物化学与西部植物资源持续利用国家重点实验室_期刊论文

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Recommended Citation:
Fuji, K; Yang, XS; Tanaka, K; Asakawa, N; Hao, XJ.1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones,TETRAHEDRON LETTERS,1996,37(41):7373-7376
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