1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones
Fuji, K; Yang, XS; Tanaka, K; Asakawa, N; Hao, XJ
1996-10-07
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume37Issue:41Pages:7373-7376
AbstractHalf esters (R)-5 of 1,1'-binaphthalene-8,8'-diol undergo 1,4-addition of lithium dialkyl cuprates followed by formal 1,2-addition to give beta-substituted ketones (S)-6 or (S)-7 with high enantioselectivity (96 similar to 100% ee). A brief discussion of the mechanism is presented. Copyright (C) 1996 Elsevier Science Ltd
KeywordOne-step Synthesis Esters
Subject AreaChemistry, Organic
Indexed Bysci
Language英语
WOS IDWOS:A1996VL42100013
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/4344
Collection植物化学与西部植物资源持续利用国家重点实验室
AffiliationCHINESE ACAD SCI,KUNMING INST BOT,YUNNAN 650204,PEOPLES R CHINA
Recommended Citation
GB/T 7714
Fuji, K,Yang, XS,Tanaka, K,et al. 1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones[J]. TETRAHEDRON LETTERS,1996,37(41):7373-7376.
APA Fuji, K,Yang, XS,Tanaka, K,Asakawa, N,&Hao, XJ.(1996).1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones.TETRAHEDRON LETTERS,37(41),7373-7376.
MLA Fuji, K,et al."1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones".TETRAHEDRON LETTERS 37.41(1996):7373-7376.
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