| Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes |
| Dai, WM; Zhu, HJ; Hao, XJ
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| 1996-08-12
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| 发表期刊 | TETRAHEDRON LETTERS
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| ISSN | 0040-4039
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| 卷号 | 37期号:33页码:5971-5974 |
| 摘要 | Asymmetric Pictet-Spengler reaction of a number of aldehydes with Abrine methyl ester (1) was performed at room temperature to furnish mainly 3 and high ee was obtained in enantioselective addition of Et(2)Zn with PhCHO catalyzed by chiral 1,2,3,4-tetrahydro-beta-carboline derivatives 5 synthesized from 3. Copyright (C) 1996 Elsevier Science Ltd |
| 关键词 | Highly Enantioselective Addition
Aprotic Media
Enantiospecific Synthesis
Amino-alcohols
Alkaloids
Reagents
Stereospecificity
Dialkylzincs
(-)-suaveoline
(-)-raumacline
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| 学科领域 | Chemistry, Organic
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| 收录类别 | sci
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| 语种 | 英语
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| WOS记录号 | WOS:A1996VB81400038
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| 引用统计 |
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| 文献类型 | 期刊论文
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| 条目标识符 | http://ir.kib.ac.cn/handle/151853/4332
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| 专题 | 植物化学与西部植物资源持续利用国家重点实验室
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| 作者单位 | CHINESE ACAD SCI,KUNMING INST BOT,KUNMING 650204,YUNNAN,PEOPLES R CHINA
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推荐引用方式
GB/T 7714 |
Dai, WM,Zhu, HJ,Hao, XJ. Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes[J]. TETRAHEDRON LETTERS,1996,37(33):5971-5974.
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| APA |
Dai, WM,Zhu, HJ,&Hao, XJ.(1996).Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes.TETRAHEDRON LETTERS,37(33),5971-5974.
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| MLA |
Dai, WM,et al."Chiral ligands derived from Abrine .3. Asymmetric Pictet-Spengler reaction of Abrine methyl ester and synthesis of chiral 1,2,3,4-tetrahydro-beta-carbolines as promoters in addition of diethylzinc toward aromatic aldehydes".TETRAHEDRON LETTERS 37.33(1996):5971-5974.
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