A formal asymmetric synthesis of calabar bean alkaloids | |
Node, M; Hao, XJ![]() | |
1996-04-01 | |
发表期刊 | CHEMICAL & PHARMACEUTICAL BULLETIN
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ISSN | 0009-2363 |
卷号 | 44期号:4页码:715-719 |
摘要 | A total synthesis of (-)-eserethole (2) has been accomplished using the Diels-Alder reaction of (S)-(-)-2-methyl-2- [Z-(E)-nitroethenyl]-delta-valerolactone (3) and Danishefsky's diene as a key step, The synthesis of optically pure (-)-eserethole (2) constitutes a formal synthesis of naturally occurring Calabar bean alkaloids, such as (-)-physostigmine (1), (-)-physovenine (17) and(-)-geneserine (18). |
关键词 | (-)-eserethole (-)-physostigmine Asymmetric Nitroolefination Diels-alder Reaction Nitro Group Aromatization |
学科领域 | Chemistry, Medicinal ; Chemistry, Multidisciplinary ; Pharmacology & Pharmacy |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:A1996UG30100015 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/4068 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.ACAD SINICA, KUNMING INST BOT, KUNMING 650204, YUNNAN, PEOPLES R CHINA 2.KYOTO UNIV, CHEM RES INST, UJI, KYOTO 611, JAPAN |
推荐引用方式 GB/T 7714 | Node, M,Hao, XJ,Nishide, K,et al. A formal asymmetric synthesis of calabar bean alkaloids[J]. CHEMICAL & PHARMACEUTICAL BULLETIN,1996,44(4):715-719. |
APA | Node, M,Hao, XJ,Nishide, K,&Fuji, K.(1996).A formal asymmetric synthesis of calabar bean alkaloids.CHEMICAL & PHARMACEUTICAL BULLETIN,44(4),715-719. |
MLA | Node, M,et al."A formal asymmetric synthesis of calabar bean alkaloids".CHEMICAL & PHARMACEUTICAL BULLETIN 44.4(1996):715-719. |
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