A formal asymmetric synthesis of calabar bean alkaloids

	A formal asymmetric synthesis of calabar bean alkaloids
	Node, M ; Hao, XJ; Nishide, K ; Fuji, K
	1996-04-01
发表期刊	CHEMICAL & PHARMACEUTICAL BULLETIN
ISSN	0009-2363
卷号	44 期号:4 页码:715-719
摘要	A total synthesis of (-)-eserethole (2) has been accomplished using the Diels-Alder reaction of (S)-(-)-2-methyl-2- [Z-(E)-nitroethenyl]-delta-valerolactone (3) and Danishefsky's diene as a key step, The synthesis of optically pure (-)-eserethole (2) constitutes a formal synthesis of naturally occurring Calabar bean alkaloids, such as (-)-physostigmine (1), (-)-physovenine (17) and(-)-geneserine (18).
关键词	(-)-eserethole (-)-physostigmine Asymmetric Nitroolefination Diels-alder Reaction Nitro Group Aromatization
学科领域	Chemistry, Medicinal ; Chemistry, Multidisciplinary ; Pharmacology & Pharmacy
收录类别	SCI
语种	英语
WOS记录号	WOS:A1996UG30100015
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/4068
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.ACAD SINICA, KUNMING INST BOT, KUNMING 650204, YUNNAN, PEOPLES R CHINA 2.KYOTO UNIV, CHEM RES INST, UJI, KYOTO 611, JAPAN
推荐引用方式 GB/T 7714	Node, M,Hao, XJ,Nishide, K,et al. A formal asymmetric synthesis of calabar bean alkaloids[J]. CHEMICAL & PHARMACEUTICAL BULLETIN,1996,44(4):715-719.
APA	Node, M,Hao, XJ,Nishide, K,&Fuji, K.(1996).A formal asymmetric synthesis of calabar bean alkaloids.CHEMICAL & PHARMACEUTICAL BULLETIN,44(4),715-719.
MLA	Node, M,et al."A formal asymmetric synthesis of calabar bean alkaloids".CHEMICAL & PHARMACEUTICAL BULLETIN 44.4(1996):715-719.

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