Palhinine A, a Novel Alkaloid from Palhinhaea cernua
Zhao, Fu-Wei1,2; Sun, Qian-Yun3,4; Yang, Fu-Mei3,4; Hu, Guang-Wan1; Luo, Ji-Feng1; Tang, Gui-Hua1,2; Wang, Yue-Hu1; Long, Chun-Lin1,5
2010-09-03
发表期刊ORGANIC LETTERS
ISSN1523-7060
卷号12期号:17页码:3922-3925
摘要Palhinine A, a novel C(16)N-type Lycopodium alkaloid with a unique 5/6/6/9 tetracyclic ring system, was isolated from the whole plant of Palhinhaea cernua L. (Lycopodiaceae). Its structure was elucidated by spectroscopic methods, and the absolute configuration was determined by single-crystal X-ray diffraction analysis using the Flack parameter. Palhinine A is reported as the first example of Lycopodium alkaloids of which C-16 is fused to a new ring through a C-16 C-4 lingkage.
资助信息This work was funded by the National Natural Science Foundation of China (No. 20972166), the National Basic Research Program of China (973 Program) (No. 2009CB526512), the Ministry of Education of China through its 111 and 985 Projects (B08044 and MUC 985), and the Knowledge Innovation Project of the Chinese Academy of Sciences. We appreciate Dr. Jia-Liang Zhong who works at the Shanghai Institute of Pharmaceutical Industry, who measured and elucidated the crystal structure, and Dr. Xiao-Nian Li at the Kunming Institute of Botany for his help in the experiment. We are also grateful to Adam Kavalier, who is a phytochemist at the Lehman College, the City University of New York, New York, for editing the English.
收录类别SCI ; IC
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/3206
专题资源植物与生物技术所级重点实验室
作者单位1.Chinese Acad Sci, Key Lab Econ Plants & Biotechnol, Kunming Inst Bot, Kunming 650204, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Guiyang 550002, Peoples R China
4.Key Lab Chem Nat Prod, Guiyang, Guizhou Prov, Peoples R China
5.Minzu Univ China, Coll Life & Environm Sci, Beijing 100081, Peoples R China
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Zhao, Fu-Wei,Sun, Qian-Yun,Yang, Fu-Mei,et al. Palhinine A, a Novel Alkaloid from Palhinhaea cernua[J]. ORGANIC LETTERS,2010,12(17):3922-3925.
APA Zhao, Fu-Wei.,Sun, Qian-Yun.,Yang, Fu-Mei.,Hu, Guang-Wan.,Luo, Ji-Feng.,...&Long, Chun-Lin.(2010).Palhinine A, a Novel Alkaloid from Palhinhaea cernua.ORGANIC LETTERS,12(17),3922-3925.
MLA Zhao, Fu-Wei,et al."Palhinine A, a Novel Alkaloid from Palhinhaea cernua".ORGANIC LETTERS 12.17(2010):3922-3925.
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