A novel direct conversion of primary amides to their corresponding methyl esters

doi:10.1002/ejoc.200600853

	A novel direct conversion of primary amides to their corresponding methyl esters
	Li, Liang-Chun ; Ren, Jie ; Liao, Tou-Gen ; Jiang, Ju-Xing ; Zhu, Hua-Jie
通讯作者	hjzhu@mail.kib.ac.cn
	2007-02-01
发表期刊	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN	1434-193X
期号	6 页码:1026-1030
摘要	A novel method was used to directly convert aliphatic and aromatic primary amides into their corresponding methyl esters in high yields (up to 99%) under mild reaction conditions. Possible mechanisms were studied at the B3LYP/6-31++G(d,p) level of theory. Formation of the ester proceeded through a rearrangement of the -OMe and -NH2 groups in the RC(O)NHS(O)OMe intermediate in a H+-catalyzed six-membered ring transition state structure. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
关键词	Amides Esters Reaction Mechanisms Density Functional Calculations
学科领域	Chemistry, Organic
DOI	10.1002/ejoc.200600853
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000244578900018
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/2965
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.CAS, Organ Synth & Nat Prod Lab, Kunming Inst Bot, Kunming 650204, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Li, Liang-Chun,Ren, Jie,Liao, Tou-Gen,et al. A novel direct conversion of primary amides to their corresponding methyl esters[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2007(6):1026-1030.
APA	Li, Liang-Chun,Ren, Jie,Liao, Tou-Gen,Jiang, Ju-Xing,&Zhu, Hua-Jie.(2007).A novel direct conversion of primary amides to their corresponding methyl esters.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(6),1026-1030.
MLA	Li, Liang-Chun,et al."A novel direct conversion of primary amides to their corresponding methyl esters".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .6(2007):1026-1030.

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