A novel direct conversion of primary amides to their corresponding methyl esters
Li, Liang-Chun; Ren, Jie; Liao, Tou-Gen; Jiang, Ju-Xing; Zhu, Hua-Jie
2007-02-01
发表期刊EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN1434-193X
期号6页码:1026-1030
摘要A novel method was used to directly convert aliphatic and aromatic primary amides into their corresponding methyl esters in high yields (up to 99%) under mild reaction conditions. Possible mechanisms were studied at the B3LYP/6-31++G(d,p) level of theory. Formation of the ester proceeded through a rearrangement of the -OMe and -NH2 groups in the RC(O)NHS(O)OMe intermediate in a H+-catalyzed six-membered ring transition state structure. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
关键词Amides Esters Reaction Mechanisms Density Functional Calculations
学科领域Chemistry, Organic
DOI10.1002/ejoc.200600853
收录类别SCI ; CCR
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000244578900018
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/2965
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.CAS, Organ Synth & Nat Prod Lab, Kunming Inst Bot, Kunming 650204, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Li, Liang-Chun,Ren, Jie,Liao, Tou-Gen,et al. A novel direct conversion of primary amides to their corresponding methyl esters[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2007(6):1026-1030.
APA Li, Liang-Chun,Ren, Jie,Liao, Tou-Gen,Jiang, Ju-Xing,&Zhu, Hua-Jie.(2007).A novel direct conversion of primary amides to their corresponding methyl esters.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(6),1026-1030.
MLA Li, Liang-Chun,et al."A novel direct conversion of primary amides to their corresponding methyl esters".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .6(2007):1026-1030.
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