Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H
Pan, Zhiqiang1; Qin, Xu-Jie1; Liu, Ya-Ping1; Wu, Ting1,2; Luo, Xiao-Dong1; Xie, Chengfeng1
2016-02-19
Source PublicationORGANIC LETTERS
Volume18Issue:4Pages:654-657
AbstractAlstoscholarisines H-J (1-3), new monoterpenoid indole alkaloids with an unprecedented skeleton created via the formation of a C-3/N-1 bond, were isolated from Alstonia scholaris. Their structures were established by extensive spectroscopic analyses and the assessment of single-crystal X-ray diffraction data. The total synthesis of alstoscholarisine H was achieved via the regioselective nucleophilic addition of pyridinium through a bioinspired iminium ion intermediate followed by Pictet-Spengler-like cyclization.
DOI10.1021/acs.orglett.5b03583
Indexed BySCI
Language英语
WOS IDWOS:000370768200007
Citation statistics
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/25987
Collection植物化学与西部植物资源持续利用国家重点实验室
Affiliation1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Pan, Zhiqiang,Qin, Xu-Jie,Liu, Ya-Ping,et al. Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H[J]. ORGANIC LETTERS,2016,18(4):654-657.
APA Pan, Zhiqiang,Qin, Xu-Jie,Liu, Ya-Ping,Wu, Ting,Luo, Xiao-Dong,&Xie, Chengfeng.(2016).Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H.ORGANIC LETTERS,18(4),654-657.
MLA Pan, Zhiqiang,et al."Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H".ORGANIC LETTERS 18.4(2016):654-657.
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