Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H
Li, Liang-Qun1,2,3; Li, Ming-Ming2; Chen, Dong2,3; Liu, Hao-Miao2,3; Geng, Hui-Chun2,3; Lin, Jun1; Qin, Hong-Bo2; Lin,J (reprint author),Yunnan Univ,Sch Chem Sci & Technol,Key Lab Med Chem Nat Resources,Minist Educ,Kunming 650091,Peoples R China.; linjun@ynu.edu.cn; qinhongbo@mail.kib.ac.cn
2014-10-22
发表期刊TETRAHEDRON LETTERS
ISSN0040-4039
卷号55期号:43页码:5960-5962
摘要Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H has been achieved. Key step involved construction of all-carbon quaternary carbon by palladium-catalyzed conjugate addition of arylboronic acid to 3-methyl cyclohexenone. Furthermore, a new approach to build [6-5-6] tricyclic backbone via formyl introduction and subsequent aldol-type condensation was also explored. (C) 2014 Elsevier Ltd. All rights reserved.
关键词Stereoselective Formal Synthesis (+)-dichroanone (+)-taiwaniaquinone h Conjugate Addition Reetz Reagent
资助信息National Natural Science Foundation of China [21372229]; Natural Science Foundation of Yunnan Province [2013FB064]; Program of 'One Hundred Talented People'
收录类别SCI ; IC
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/18391
专题植物化学与西部植物资源持续利用国家重点实验室
通讯作者Lin,J (reprint author),Yunnan Univ,Sch Chem Sci & Technol,Key Lab Med Chem Nat Resources,Minist Educ,Kunming 650091,Peoples R China.; linjun@ynu.edu.cn; qinhongbo@mail.kib.ac.cn
作者单位1.Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resources, Minist Educ, Kunming 650091, Peoples R China
2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Li, Liang-Qun,Li, Ming-Ming,Chen, Dong,et al. Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H[J]. TETRAHEDRON LETTERS,2014,55(43):5960-5962.
APA Li, Liang-Qun.,Li, Ming-Ming.,Chen, Dong.,Liu, Hao-Miao.,Geng, Hui-Chun.,...&qinhongbo@mail.kib.ac.cn.(2014).Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H.TETRAHEDRON LETTERS,55(43),5960-5962.
MLA Li, Liang-Qun,et al."Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H".TETRAHEDRON LETTERS 55.43(2014):5960-5962.
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