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题名: Longphyllinesides A and B: natural Diels-Alder adducts from Daphniphyllum longeracemosum?
作者: Di, Ying-Tong1; Wee, Chorng-Shin2; Li, Chun-Shun1; Kong, Ning-Chuan4; Wang, Jun-Song1; Fang, Xin1; Zhu, Hua-Jie1; Wu, Yun-Dong2, 3; null(郝小江)1
刊名: TETRAHEDRON
关键词: Daphniphyllum longeracemosum ; Alkaloid ; Biogenetic pathway ; Chemical computation ; Diels-Alderase
英文摘要: Two new alkaloids, longphyllinesides A (1) and B (2), were isolated from Daphniphyllum longeracemosum. Their structures were elucidated using 1D and 2D NMR spectra. The key step in their biogenetic pathway is indicated to be Diels-Alder cycloaddition via asynchronous concerted mechanism by density functional theory calculations. The possibility of involvement of a Diels-Alderase is also discussed. (C) 2014 Elsevier Ltd. All rights reserved.
出版日期: 2014-07-01
卷号: 70, 期号:26, 页码:4017-4021
语种: 英语
收录类别: SCI ; IC
学科分类: Chemistry, Organic
ISSN号: 0040-4020
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.kib.ac.cn/handle/151853/18183
Appears in Collections:植物化学与西部植物资源持续利用国家重点实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
2.Hong Kong Univ Sci & Technol, Kowloon, Hong Kong, Peoples R China
3.Peking Univ, Shenzhen Grad Sch, Lab Chem Gen, Shenzhen 518055, Peoples R China
4.Yunnan Acad Tobacco Sci, Kunming 650106, Yunnan, Peoples R China

Recommended Citation:
Di,Ying-Tong;Wee,Chorng-Shin;Li,Chun-Shun;Kong,Ning-Chuan;Wang,Jun-Song;Fang,Xin;Zhu,Hua-Jie;Wu,Yun-Dong;Hao,Xiao-Jiang.Longphyllinesides A and B: natural Diels-Alder adducts from Daphniphyllum longeracemosum?,TETRAHEDRON,2014,70(26):4017-4021
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