| One-Step Semisynthesis Method of Spirocurcasone and Pyracurcasone from Curcusones A and B | |
Li, Xu-Yang1,2; Yang, Yuan-Feng1,2; Peng, Xing-Rong1,2; Li, Ming-Ming1; Li, Liang-Qun1,2; Deng, Xu1 ; Qin, Hong-Bo1,2; Liu, Jie-Qing1; Qiu, Ming-Hua1,2
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| 通讯作者 | Qin,HB (reprint author),Chinese Acad Sci,Kunming Inst Bot,State Key Lab Photochem & Plant Resources West,Kunming 650201,Yunnan,Peoples R China. ; mhchiu@mail.kib.ac.cn ; liujieqing@mail.kib.ac.cn ; qinhongbo@mail.kib.ac.cn |
| 2014-04-18 | |
| 发表期刊 | ORGANIC LETTERS
 |
| ISSN | 1523-7060 |
| 卷号 | 16期号:8页码:2196-2199 |
| 摘要 | High contents of curcusones A and B and trace amounts of spirocurcasone exist in the roots of Jatropha curcas. Here, a one-step semisynthesis method of spirocurcasone and pyracurcasone was built, not only resulted an increased yield of spirocurcasone but also produced pyracurcasone, which exhibited greater cytotoxicity compared to curcusones A and B. The plausible mechanism of the formation of pyracurcasone was proposed, and the proposed biogenetic origin for spirocurcasone by Taglialatela-Scafati was confirmed. |
| 关键词 | Jatropha-curcas Diterpenes Dumsin System |
| 学科领域 | Chemistry |
| DOI | 10.1021/ol500692j |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000334823600032 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.kib.ac.cn/handle/151853/18126 |
| 专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Photochem & Plant Resources West, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xu-Yang,Yang, Yuan-Feng,Peng, Xing-Rong,et al. One-Step Semisynthesis Method of Spirocurcasone and Pyracurcasone from Curcusones A and B[J]. ORGANIC LETTERS,2014,16(8):2196-2199. |
| APA | Li, Xu-Yang.,Yang, Yuan-Feng.,Peng, Xing-Rong.,Li, Ming-Ming.,Li, Liang-Qun.,...&Qiu, Ming-Hua.(2014).One-Step Semisynthesis Method of Spirocurcasone and Pyracurcasone from Curcusones A and B.ORGANIC LETTERS,16(8),2196-2199. |
| MLA | Li, Xu-Yang,et al."One-Step Semisynthesis Method of Spirocurcasone and Pyracurcasone from Curcusones A and B".ORGANIC LETTERS 16.8(2014):2196-2199. |
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