New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane

doi:10.1016/j.tetlet.2014.03.100

	New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane
	Pei, Yu-Ning 1; Deng, Yu 1,2; Li, Jing-Liarig 1; Liu, Li1 ; Zhu, Hua-Jie 1
通讯作者	Zhu,HJ (reprint author),Hebei Univ,Coll Pharm Sci,Chinese Ctr Chiral,Key Lab Med Chem & Mol Diagnost,Minist Educ,Baoding 071002,Hebei,Peoples R China. ; zhuhuajie@hotmail.com
	2014-04-30
发表期刊	TETRAHEDRON LETTERS
ISSN	0040-4039
卷号	55 期号:18 页码:2948-2952
摘要	New axial N,N'-dioxide secondary amide derived from r-tryptophan was synthesized and firstly employed in catalytic enantioselective reduction of ketoimines with trichlorosilane. It was found that 4f was an effective catalyst with excellent reactivity and good enantioselectivity. Possible mechanism for the catalytic procedure was tentatively proposed. (C) 2014 Elsevier Ltd. All rights reserved.
关键词	Biscarboline N-o Amides Enantioselective Reduction Ketoimines Trichlorosilane
学科领域	Chemistry
DOI	10.1016/j.tetlet.2014.03.100
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000336114800013
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/18110
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Hebei Univ, Coll Pharm Sci, Chinese Ctr Chiral, Key Lab Med Chem & Mol Diagnost,Minist Educ, Baoding 071002, Hebei, Peoples R China 2.Kunming Inst Bot, State Key Lab Photochem & Plant Resources West Ch, Kunming 650204, Yunnan, Peoples R China
推荐引用方式 GB/T 7714	Pei, Yu-Ning,Deng, Yu,Li, Jing-Liarig,et al. New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane[J]. TETRAHEDRON LETTERS,2014,55(18):2948-2952.
APA	Pei, Yu-Ning,Deng, Yu,Li, Jing-Liarig,Liu, Li,&Zhu, Hua-Jie.(2014).New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane.TETRAHEDRON LETTERS,55(18),2948-2952.
MLA	Pei, Yu-Ning,et al."New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane".TETRAHEDRON LETTERS 55.18(2014):2948-2952.

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