Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry

doi:10.1016/j.ijms.2014.01.021

	Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry
	Geng, Chang-An1 ; Chen, Hao 1; Chen, Xing-Long 1; Zhang, Xue-Mei1 ; Lei, Li-Gong 2; Chen, Ji-Jun1
通讯作者	Chen, JJ (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, 132 Lanhei Rd, Kunming 650201, Peoples R China. ; chenjj@mail.kib.ac.cn
	2014-03-15
发表期刊	INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
ISSN	1387-3806
卷号	361 页码:9-22
摘要	Saniculiphyllum guangxiense as a highly distinctive species within Saxifragaceae is fallen to the critically endangered category, whose chemical and taxonomic information is still little-known. The first time LC-DAD/MSn investigation on S. guangxiense led to the detection and characterization of 50 compounds, involving cyanogenic glycosides, phenolic sulfates, triterpenoids, amino acids, phenyl-propanoids, aromatic derivatives, lignans, flavonoids, nucleosides, fatty acids and carbohydrate, based on their fragmentation characteristics, UV spectra or comparison with the reference compounds. The collision induced dissociation (CID) fragmentation patterns for several types of compounds were also concluded. The main constituents of S. guangxiense were revealed as cyanogenic glycosides, triterpenoids, phenolic sulfates and organic acids, which were very different from other Saxifragaceae plants. This paper will provide valuable information for understanding its chemical profiles and taxonomic position in Saxifragaceae from a chemotaxonomic point of view. (C) 2014 Elsevier B.V. All rights reserved.
关键词	Lc-dad/esi-msn Saniculiphyllum Guangxiense Cyanogenic Glycosides Triterpenoids Phenolic Sulfates
学科领域	Physics, Atomic, Molecular & Chemical ; Spectroscopy
DOI	10.1016/j.ijms.2014.01.021
收录类别	SCI
语种	英语
WOS记录号	WOS:000334085200002
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/18042
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China 2.Chinese Acad Sci, Kunming Inst Bot, Key Lab Biodivers & Biogeog, Kunming 650201, Peoples R China
推荐引用方式 GB/T 7714	Geng, Chang-An,Chen, Hao,Chen, Xing-Long,et al. Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,2014,361:9-22.
APA	Geng, Chang-An,Chen, Hao,Chen, Xing-Long,Zhang, Xue-Mei,Lei, Li-Gong,&Chen, Ji-Jun.(2014).Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry.INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,361,9-22.
MLA	Geng, Chang-An,et al."Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry".INTERNATIONAL JOURNAL OF MASS SPECTROMETRY 361(2014):9-22.

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