Total synthesis of (+/-)-brazilin and formal synthesis of (+/-)-brazilein, (+/-)-brazilide A using m-CPBA
Li, Liang-Qun1,2; Li, Ming-Ming1; Wang, Kou3; Qin, Hong-Bo1
2013-11-06
发表期刊TETRAHEDRON LETTERS
ISSN0040-4039
卷号54期号:45页码:6029-6031
摘要Total synthesis of (+/-)-brazilin has been accomplished. m-CPBA epoxidation of allyl alcohol 10 and epoxy opening reaction mediated by m-chlorobenzoic acid, formed in situ as a byproduct, gave advanced intermediate diol 14. O-alkylation and cyclization gave phenol 6 which enabled the formal synthesis of (+/-)-brazilein and (+/-)-brazilide A. (C) 2013 Elsevier Ltd. All rights reserved.
关键词Total Synthesis Brazilin Brazilein Brazilide a M-cpba
资助信息National Natural Science Foundation of China [21372229]
收录类别SCI ; IC ; CCR
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/17276
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Kunming Med Univ, Yunnan Key Lab Pharmacol Nat Prod, Sch Pharmaceut Sci, Kunming 650500, Peoples R China
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GB/T 7714
Li, Liang-Qun,Li, Ming-Ming,Wang, Kou,et al. Total synthesis of (+/-)-brazilin and formal synthesis of (+/-)-brazilein, (+/-)-brazilide A using m-CPBA[J]. TETRAHEDRON LETTERS,2013,54(45):6029-6031.
APA Li, Liang-Qun,Li, Ming-Ming,Wang, Kou,&Qin, Hong-Bo.(2013).Total synthesis of (+/-)-brazilin and formal synthesis of (+/-)-brazilein, (+/-)-brazilide A using m-CPBA.TETRAHEDRON LETTERS,54(45),6029-6031.
MLA Li, Liang-Qun,et al."Total synthesis of (+/-)-brazilin and formal synthesis of (+/-)-brazilein, (+/-)-brazilide A using m-CPBA".TETRAHEDRON LETTERS 54.45(2013):6029-6031.
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