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题名: Formal Synthesis of Aspidospermidine via the Intramolecular Cascade Transannular Cyclization
作者: Huang, Jiu-Zhong1, 2; Jie, Xiao-Ke1, 3; Wei, Kun1; Zhang, Hongbin2; Wang, Min-Cai3; null(杨玉荣)1
刊名: SYNLETT
关键词: alkaloid ; total synthesis ; palladium ; cross-coupling ; cyclization
英文摘要: A formal synthesis of aspidospermidine is reported through a novel preparation of Stork's penultimate tricyclic ketone intermediate. The key steps of the synthesis consist of an intramolecular cascade transannular cyclization, triggered by the removal of Boc group, which simultaneously forms the C, D, and E rings of aspidospermidine and conveniently setting up the quaternary stereo-center via decarboxylative alkylation reaction of the beta-keto ester.
出版日期: 2013-06-01
卷号: 24, 期号:10, 页码:1303-1306
语种: 英语
收录类别: SCI ; IC ; CCR
学科分类: Chemistry, Organic
ISSN号: 0936-5214
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.kib.ac.cn/handle/151853/16779
Appears in Collections:植物化学与西部植物资源持续利用国家重点实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China
2.Yunnan Univ, Key Lab Med Chem Nat Resource, Kunming 650091, Peoples R China
3.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

Recommended Citation:
Huang, Jiu-Zhong; Jie, Xiao-Ke; Wei, Kun; Zhang, Hongbin; Wang, Min-Cai; Yang, Yu-Rong.Formal Synthesis of Aspidospermidine via the Intramolecular Cascade Transannular Cyclization,SYNLETT,2013,(10):1303-1306
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