Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane
Pan, Wei1,4; Deng, Yu1,4; He, Jiang-Bo1,4; Bai, Bing1; Zhu, Hua-Jie1,2,3
Corresponding AuthorZhu, HJ (reprint author), Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China. ; hjzhu@mail.-kib.ac.cn
2013-09-02
Source PublicationTETRAHEDRON
ISSN0040-4020
Volume69Issue:35Pages:7253-7257
AbstractA novel asymmetric-axle-supported chiral N-O amide was synthesized and used in catalytic enantioselective hydrosilylation of N-aryl ketimines with HSiCl3 at room temperature instead of the typical -20 degrees C. High conversion yield and high enantioselectivity up to 96% were observed. (C) 2013 The Authors. Published by Elsevier Ltd. All rights reserved.
KeywordAsymmetric-axle-supported Hydrosilylation Ketimines Trichlorosilane
Subject AreaChemistry, Organic
DOI10.1016/j.tet.2013.06.081
Indexed BySCI ; IC ; CCR
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000322557500007
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/16663
Collection植物化学与西部植物资源持续利用国家重点实验室
Affiliation1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China
2.Hebei Univ, Key Lab Med Chem & Mol Diag, Minist Educ, Baoding 071002, Peoples R China
3.Hebei Univ, Sch Life Sci, Baoding 071002, Peoples R China
4.Grad Univ CAS, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Pan, Wei,Deng, Yu,He, Jiang-Bo,et al. Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane[J]. TETRAHEDRON,2013,69(35):7253-7257.
APA Pan, Wei,Deng, Yu,He, Jiang-Bo,Bai, Bing,&Zhu, Hua-Jie.(2013).Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane.TETRAHEDRON,69(35),7253-7257.
MLA Pan, Wei,et al."Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane".TETRAHEDRON 69.35(2013):7253-7257.
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