Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane
Pan, Wei1,4; Deng, Yu1,4; He, Jiang-Bo1,4; Bai, Bing1; Zhu, Hua-Jie1,2,3
2013-09-02
发表期刊TETRAHEDRON
ISSN0040-4020
卷号69期号:35页码:7253-7257
摘要A novel asymmetric-axle-supported chiral N-O amide was synthesized and used in catalytic enantioselective hydrosilylation of N-aryl ketimines with HSiCl3 at room temperature instead of the typical -20 degrees C. High conversion yield and high enantioselectivity up to 96% were observed. (C) 2013 The Authors. Published by Elsevier Ltd. All rights reserved.
关键词Asymmetric-axle-supported Hydrosilylation Ketimines Trichlorosilane
资助信息973 Program [2009CB 522300]; Hebei University
学科领域Chemistry, Organic
DOI10.1016/j.tet.2013.06.081
收录类别SCI ; IC ; CCR
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000322557500007
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/16663
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China
2.Hebei Univ, Key Lab Med Chem & Mol Diag, Minist Educ, Baoding 071002, Peoples R China
3.Hebei Univ, Sch Life Sci, Baoding 071002, Peoples R China
4.Grad Univ CAS, Beijing, Peoples R China
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Pan, Wei,Deng, Yu,He, Jiang-Bo,et al. Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane[J]. TETRAHEDRON,2013,69(35):7253-7257.
APA Pan, Wei,Deng, Yu,He, Jiang-Bo,Bai, Bing,&Zhu, Hua-Jie.(2013).Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane.TETRAHEDRON,69(35),7253-7257.
MLA Pan, Wei,et al."Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane".TETRAHEDRON 69.35(2013):7253-7257.
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