Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum
Liu, Hong-Xin1,2; Chen, Kai3; Sun, Qian-Yun4,5; Yang, Fu-Mei4,5; Hu, Guang-Wan1; Wang, Yue-Hu1; Long, Chun-Lin1,6
2013-04-01
发表期刊JOURNAL OF NATURAL PRODUCTS
ISSN0163-3864
卷号76期号:4页码:732-736
摘要A new complex natural product with a C-39 skeleton, named nudibaccatumone, and the known sesquiterpenes (+)-spathulenol, (-)-4 beta,10 alpha-aromadendranediol, and ent-T-muurolol, as well as the phenylpropanoid hydroxychavicol, were isolated from the aerial parts of Piper nudibaccatum. The structure and absolute configuration of nudibaccatumone were elucidated using spectroscopic methods and ECD calculations. A 1,8-Michael addition reaction and an intermolecular, inverse electron demand Diels-Alder reaction are proposed as the key steps in the biosynthesis of nudibaccatumone.
关键词Inhibitors Density Assay
资助信息National Natural Science Foundation of China [20972166, 21133002, 31070288, 31161140345]; Ministry of Education of China [B08044, MUC985-9]; Ministry of Science and Technology of China [2012FY110300, 2008FY110400-2-2]; Natural Science Foundation of Yunnan Province, China [2011FZ205]; Shenzhen Peacock Program
学科领域Plant Sciences ; Chemistry, Medicinal ; Pharmacology & Pharmacy
收录类别SCI ; IC
语种英语
WOS研究方向Plant Sciences ; Pharmacology & Pharmacy
WOS类目Plant Sciences ; Chemistry, Medicinal ; Pharmacology & Pharmacy
WOS记录号WOS:000318264700036
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/16607
专题资源植物与生物技术所级重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, Key Lab Econ Plants & Biotechnol, Kunming 650201, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Peking Univ, Shenzhen Grad Sch, Lab Chem Genom, Lab Computat Chem & Drug Design, Shenzhen 518055, Peoples R China
4.Key Lab Chem Nat Prod, Guiyang 550002, Peoples R China
5.Chinese Acad Sci, Guiyang 550002, Peoples R China
6.Minzu Univ China, Coll Life & Environm Sci, Beijing 100081, Peoples R China
推荐引用方式
GB/T 7714
Liu, Hong-Xin,Chen, Kai,Sun, Qian-Yun,et al. Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum[J]. JOURNAL OF NATURAL PRODUCTS,2013,76(4):732-736.
APA Liu, Hong-Xin.,Chen, Kai.,Sun, Qian-Yun.,Yang, Fu-Mei.,Hu, Guang-Wan.,...&Long, Chun-Lin.(2013).Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum.JOURNAL OF NATURAL PRODUCTS,76(4),732-736.
MLA Liu, Hong-Xin,et al."Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum".JOURNAL OF NATURAL PRODUCTS 76.4(2013):732-736.
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