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Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum
Liu, Hong-Xin1,2; Chen, Kai3; Sun, Qian-Yun4,5; Yang, Fu-Mei4,5; Hu, Guang-Wan1; Wang, Yue-Hu1; Long, Chun-Lin1,6
Corresponding AuthorWang, YH (reprint author), Chinese Acad Sci, Kunming Inst Bot, Key Lab Econ Plants & Biotechnol, Kunming 650201, Peoples R China. ; wangyuehu@mail.kib.ac.cn ; long@mail.kib.ac.cn
2013-04-01
Source PublicationJOURNAL OF NATURAL PRODUCTS
ISSN0163-3864
Volume76Issue:4Pages:732-736
AbstractA new complex natural product with a C-39 skeleton, named nudibaccatumone, and the known sesquiterpenes (+)-spathulenol, (-)-4 beta,10 alpha-aromadendranediol, and ent-T-muurolol, as well as the phenylpropanoid hydroxychavicol, were isolated from the aerial parts of Piper nudibaccatum. The structure and absolute configuration of nudibaccatumone were elucidated using spectroscopic methods and ECD calculations. A 1,8-Michael addition reaction and an intermolecular, inverse electron demand Diels-Alder reaction are proposed as the key steps in the biosynthesis of nudibaccatumone.
KeywordInhibitors Density Assay
Subject AreaPlant Sciences ; Chemistry, Medicinal ; Pharmacology & Pharmacy
Indexed BySCI ; IC
Language英语
WOS Research AreaPlant Sciences ; Pharmacology & Pharmacy
WOS SubjectPlant Sciences ; Chemistry, Medicinal ; Pharmacology & Pharmacy
WOS IDWOS:000318264700036
Citation statistics
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/16607
Collection资源植物与生物技术所级重点实验室
Affiliation1.Chinese Acad Sci, Kunming Inst Bot, Key Lab Econ Plants & Biotechnol, Kunming 650201, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Peking Univ, Shenzhen Grad Sch, Lab Chem Genom, Lab Computat Chem & Drug Design, Shenzhen 518055, Peoples R China
4.Key Lab Chem Nat Prod, Guiyang 550002, Peoples R China
5.Chinese Acad Sci, Guiyang 550002, Peoples R China
6.Minzu Univ China, Coll Life & Environm Sci, Beijing 100081, Peoples R China
Recommended Citation
GB/T 7714
Liu, Hong-Xin,Chen, Kai,Sun, Qian-Yun,et al. Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum[J]. JOURNAL OF NATURAL PRODUCTS,2013,76(4):732-736.
APA Liu, Hong-Xin.,Chen, Kai.,Sun, Qian-Yun.,Yang, Fu-Mei.,Hu, Guang-Wan.,...&Long, Chun-Lin.(2013).Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum.JOURNAL OF NATURAL PRODUCTS,76(4),732-736.
MLA Liu, Hong-Xin,et al."Nudibaccatumone, a Trimer Comprising a Phenylpropanoid and Two Sesquiterpene Moieties from Piper nudibaccatum".JOURNAL OF NATURAL PRODUCTS 76.4(2013):732-736.
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