Analysis of mexicanolide- and phragmalin-type limonoids from Heynea trijuga using high-performance liquid chromatography/electrospray tandem mass spectrometry
Yang, Wei1; Fang, Dong-Mei2; He, Hong-Ping1; Hao, Xiao-Jiang1; Wu, Zhi-Jun2; Zhang, Guo-Lin2
2013-06-15
发表期刊RAPID COMMUNICATIONS IN MASS SPECTROMETRY
ISSN0951-4198
卷号27期号:11页码:1203-1212
摘要RATIONALE Limonoids, a class of tetranortriterpenoids, exhibit various biological effects, including acting as potent antifeedants and insect growth-regulators against various pests. The analysis of phragmalin- and mexicanolide-type limonoids by collision-induced dissociation tandem mass spectrometry (CID-MS/MS) has not been reported. METHODS A high-performance liquid chromatography/electrospray ionization (HPLC/ESI)-MS/MS method was developed to investigate the fragmentation patterns of [M+NH4]+ ions for nine reference phragmalin- and mexicanolide-type limonoids. The method was also used in the identification of limonoid compounds in botanic extracts of Heynea trijuga. RESULTS The losses of side chains and the furan part were the major fragmentation patterns. However, there was variation in the relative abundances of product ions resulting from the same fragmentation pathways. A total of 89 phragmalin- and mexicanolide-type limonoids in botanic extracts of Heynea trijuga were detected and 50 of these compounds were identified or tentatively characterized based on elemental constituents, fragmentation pathways, and the profile of the major product ions of reference compounds. In addition, the isomers could be tentatively distinguished. CONCLUSIONS An HPLC/ESI-MS/MS method was developed and could be used to simultaneously identify and screen phragmalin- and mexicanolide-type limonoids in botanic extracts of Heynea trijuga. Copyright (c) 2013 John Wiley & Sons, Ltd.
关键词Cipadessa-cinerascens Citrus Limonoids Sandoricum-koetjape Phenolic-compounds Limonin Glucoside Ionization Leaves Tetranortriterpenoids Inhibition Extracts
资助信息West Light Foundation of the Chinese Academy of Sciences [Y2C6031100]; National Natural Science Foundation of China [20932007, 21172214]; Yong Academic and Technical Leader Raising Foundation of Yunnan Province [2010CI047]
学科领域Biochemistry & Molecular Biology ; Chemistry ; Spectroscopy
收录类别SCI
语种英语
WOS研究方向Biochemistry & Molecular Biology ; Chemistry ; Spectroscopy
WOS类目Biochemical Research Methods ; Chemistry, Analytical ; Spectroscopy
WOS记录号WOS:000318626500004
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/16461
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Yunnan, Peoples R China
2.Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China
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Yang, Wei,Fang, Dong-Mei,He, Hong-Ping,et al. Analysis of mexicanolide- and phragmalin-type limonoids from Heynea trijuga using high-performance liquid chromatography/electrospray tandem mass spectrometry[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2013,27(11):1203-1212.
APA Yang, Wei,Fang, Dong-Mei,He, Hong-Ping,Hao, Xiao-Jiang,Wu, Zhi-Jun,&Zhang, Guo-Lin.(2013).Analysis of mexicanolide- and phragmalin-type limonoids from Heynea trijuga using high-performance liquid chromatography/electrospray tandem mass spectrometry.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,27(11),1203-1212.
MLA Yang, Wei,et al."Analysis of mexicanolide- and phragmalin-type limonoids from Heynea trijuga using high-performance liquid chromatography/electrospray tandem mass spectrometry".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 27.11(2013):1203-1212.
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