Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes
Bai, Bing1,2; Shen, Lan1,2; Ren, Jie1; Zhu, Hua Jie1,3
Corresponding AuthorZhu, HJ (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Lanhei Rd 132, Kunming 650204, Peoples R China, hjzhu@mail.kib.ac.cn
2012-02-01
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume354Issue:2-3Pages:354-358
AbstractThe allylation of aromatic and aliphatic aldehydes with allyltrichlorosilanes has been catalyzed with a new Lewis base organocatalyst, 1,1'-biscarboline N,N'-dioxide with high enantioselectivities of up to 99% for 4-methoxybenzaldehyde and 97% ee for cycloformaldehyde, respectively. In total, 13 heteroaryl and aliphatic aldehydes were tested.
KeywordAllylation Asymmetric Catalysis 1 1'-biscarboline n N'-dioxides Organocatalysts
Subject AreaChemistry, Applied ; Chemistry, Organic
DOI10.1002/adsc.201100592
Indexed BySCI ; IC ; CCR
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS IDWOS:000300448400013
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/10463
Collection植物化学与西部植物资源持续利用国家重点实验室
Affiliation1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
2.CAS, Grad Sch, Beijing 100049, Peoples R China
3.Hebei Univ, Key Lab Med Chem & Mol Diag, Minist Educ, Baoding 071002, Peoples R China
Recommended Citation
GB/T 7714
Bai, Bing,Shen, Lan,Ren, Jie,et al. Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes[J]. ADVANCED SYNTHESIS & CATALYSIS,2012,354(2-3):354-358.
APA Bai, Bing,Shen, Lan,Ren, Jie,&Zhu, Hua Jie.(2012).Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes.ADVANCED SYNTHESIS & CATALYSIS,354(2-3),354-358.
MLA Bai, Bing,et al."Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes".ADVANCED SYNTHESIS & CATALYSIS 354.2-3(2012):354-358.
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