Discovery of Natural Co-occurring Enantiomers of Monoterpenoid Indole Alkaloids

doi:10.1002/cjoc.202000574

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	Discovery of Natural Co-occurring Enantiomers of Monoterpenoid Indole Alkaloids
	Yu,Yang ; Bao,Mei-Fen ; Cai,Xiang-Hai
	2021
发表期刊	CHINESE JOURNAL OF CHEMISTRY
ISSN	1001-604X
卷号	39 期号:4 页码:866-872
摘要	Main observation and conclusionTwo new pairs of monoterpenoid indole alkaloids (MIAs) enantiomers as well as their new congeners were isolated from stems of Tabernaemontana bovina Lour. (Apocynaceae). Their structures were elucidated by spectroscopic analyses and confirmed by X-ray diffractions and computational calculations. Tabovine A, tabovine B and tabovines C-D possessed unprecedented 6/5/5/6/6, 6/5/5/6/5 and 6/5/6/6/6 ring systems, respectively. It is the first time to report co-occurring enantiomers of MIAs. Additionally, the explanation concerning biogenesis of MIAs was provided. The findings would open a new window where we could disclose more diverse MIAs.
关键词	Monoterpenoid indole alkaloid Enantiomers Tabovines A— D Structure elucidation\| Extraction and isolation
DOI	10.1002/cjoc.202000574
WOS记录号	WOS:000621422300001
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/73778
专题	中国科学院昆明植物研究所
作者单位	1.[Yu, Yang 2.Bao, Mei-Fen 3.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
推荐引用方式 GB/T 7714	Yu,Yang,Bao,Mei-Fen,Cai,Xiang-Hai. Discovery of Natural Co-occurring Enantiomers of Monoterpenoid Indole Alkaloids[J]. CHINESE JOURNAL OF CHEMISTRY,2021,39(4):866-872.
APA	Yu,Yang,Bao,Mei-Fen,&Cai,Xiang-Hai.(2021).Discovery of Natural Co-occurring Enantiomers of Monoterpenoid Indole Alkaloids.CHINESE JOURNAL OF CHEMISTRY,39(4),866-872.
MLA	Yu,Yang,et al."Discovery of Natural Co-occurring Enantiomers of Monoterpenoid Indole Alkaloids".CHINESE JOURNAL OF CHEMISTRY 39.4(2021):866-872.

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