Stereocontrolled concise synthesis of (+/-)-halosaline through intramolecular C-H amination | |
Meng, Chun-Yan1,2; Liang, Xiao1; Zhang, Hongbin2; Wei, Kun1; Yang, Yu-Rong1 | |
通讯作者 | Wei, Kun(weikun@mail.kib.ac.cn) ; Yang, Yu-Rong(yangyurong@mail.kib.ac.cn) |
2019-07-04 | |
发表期刊 | TETRAHEDRON LETTERS |
ISSN | 0040-4039 |
卷号 | 60期号:27页码:1781-1783 |
摘要 | Total synthesis of 2-(2-hydroxyalkyl)-piperidine alkaloid (+/-)-halosaline is described from 7-octen-4-ol using a Rh-catalyzed chemo- and diastereo-selective intramolecular C-H amination of sulfamate ester, ring-closing metathesis, and S(N)2 displacement reaction of the six-membered ring sulfamidate as the key steps. (C) 2019 Elsevier Ltd. All rights reserved. |
关键词 | C-H amination Halosaline Ring-closing metathesis Total synthesis |
DOI | 10.1016/j.tetlet.2019.05.068 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000474678100007 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/67847 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
通讯作者 | Wei, Kun; Yang, Yu-Rong |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resources, Minist Educ, Kunming 650091, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Meng, Chun-Yan,Liang, Xiao,Zhang, Hongbin,et al. Stereocontrolled concise synthesis of (+/-)-halosaline through intramolecular C-H amination[J]. TETRAHEDRON LETTERS,2019,60(27):1781-1783. |
APA | Meng, Chun-Yan,Liang, Xiao,Zhang, Hongbin,Wei, Kun,&Yang, Yu-Rong.(2019).Stereocontrolled concise synthesis of (+/-)-halosaline through intramolecular C-H amination.TETRAHEDRON LETTERS,60(27),1781-1783. |
MLA | Meng, Chun-Yan,et al."Stereocontrolled concise synthesis of (+/-)-halosaline through intramolecular C-H amination".TETRAHEDRON LETTERS 60.27(2019):1781-1783. |
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