Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates

	Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates
	Zheng, Yu 1,2; Yue, Bei-Bei 1,2; Wei, Kun 1; Yang, Yu-Rong1
	2018-12-21
发表期刊	ORGANIC LETTERS
ISSN	1523-7060
卷号	20 期号:24 页码:8035-8038
摘要	Carreira's iridium-(P, olefin) phosphoramidite-based catalytic system that allows asymmetric allyl-allylboronate cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of racemic branched allylic alcohols and allylboronate substrates. The utility of the coupling is demonstrated in a concise catalytic asymmetric synthesis of (-)-preclamol.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/64371
专题	植物化学与西部植物资源持续利用国家重点实验室
通讯作者	Yang, Yu-Rong
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Yu,Yue, Bei-Bei,Wei, Kun,et al. Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates[J]. ORGANIC LETTERS,2018,20(24):8035-8038.
APA	Zheng, Yu,Yue, Bei-Bei,Wei, Kun,&Yang, Yu-Rong.(2018).Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates.ORGANIC LETTERS,20(24),8035-8038.
MLA	Zheng, Yu,et al."Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates".ORGANIC LETTERS 20.24(2018):8035-8038.