Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates

	Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates
	Meng, Chun-Yan; Liang, Xiao; Wei, Kun; Yang, Yu-Rong
	2019-02-01
发表期刊	ORGANIC LETTERS
ISSN	1523-7060
卷号	21 期号:3 页码:840-843
摘要	Ir-catalyzed enantioselective allylic alkylation of branched racemic allylic alcohols with malonates is described. Enabled by Carreira's chiral Ir/(P, olefin) complex, the method described allows allylic substitution with various aromatic alcohols and malonates with excellent enantioselectivity. The malonates could be used directly as efficient nucleophiles without the need of preactivation.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/64242
专题	植物化学与西部植物资源持续利用国家重点实验室
通讯作者	Wei, Kun; Yang, Yu-Rong
作者单位	Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
推荐引用方式 GB/T 7714	Meng, Chun-Yan,Liang, Xiao,Wei, Kun,et al. Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates[J]. ORGANIC LETTERS,2019,21(3):840-843.
APA	Meng, Chun-Yan,Liang, Xiao,Wei, Kun,&Yang, Yu-Rong.(2019).Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates.ORGANIC LETTERS,21(3),840-843.
MLA	Meng, Chun-Yan,et al."Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates".ORGANIC LETTERS 21.3(2019):840-843.

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