ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes | |
He, Haiqing1,2,3; Qin, Hong-Bo1,2 | |
2018-06-21 | |
发表期刊 | ORGANIC CHEMISTRY FRONTIERS |
ISSN | 2052-4129 |
卷号 | 5期号:12页码:1962-1966 |
摘要 | A convenient, mild and high stereoselective C-glycosylation reaction has been developed. Glycosyl acetates were coupled with terminal alkynes via ZnBr2-activation at room temperature. Their applications were further demonstrated by the straightforward synthesis of a key intermediate in the formal synthesis of (+)-varitriol. |
DOI | 10.1039/c8qo00380g |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/61381 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Yunnan Key Lab Nat Med Chem, Kunming 650201, Yunnan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | He, Haiqing,Qin, Hong-Bo. ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(12):1962-1966. |
APA | He, Haiqing,&Qin, Hong-Bo.(2018).ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes.ORGANIC CHEMISTRY FRONTIERS,5(12),1962-1966. |
MLA | He, Haiqing,et al."ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes".ORGANIC CHEMISTRY FRONTIERS 5.12(2018):1962-1966. |
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