ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes
He, Haiqing1,2,3; Qin, Hong-Bo1,2
2018-06-21
发表期刊ORGANIC CHEMISTRY FRONTIERS
ISSN2052-4129
卷号5期号:12页码:1962-1966
摘要A convenient, mild and high stereoselective C-glycosylation reaction has been developed. Glycosyl acetates were coupled with terminal alkynes via ZnBr2-activation at room temperature. Their applications were further demonstrated by the straightforward synthesis of a key intermediate in the formal synthesis of (+)-varitriol.
DOI10.1039/c8qo00380g
语种英语
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文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/61381
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
2.Yunnan Key Lab Nat Med Chem, Kunming 650201, Yunnan, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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He, Haiqing,Qin, Hong-Bo. ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(12):1962-1966.
APA He, Haiqing,&Qin, Hong-Bo.(2018).ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes.ORGANIC CHEMISTRY FRONTIERS,5(12),1962-1966.
MLA He, Haiqing,et al."ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes".ORGANIC CHEMISTRY FRONTIERS 5.12(2018):1962-1966.
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